Learn More
Sodium bis(2-methoxyethoxy)aluminum hydride, 70% w/w in toluene.
CAS: 22722-98-1 | C6H16AlNaO4
$67.84 - $391.93
Chemical Identifiers
CAS | 22722-98-1 |
---|---|
Molecular Formula | C6H16AlNaO4 |
MDL Number | MFCD00011631 |
Synonym | Sodium dihydrobis(2-methoxyethoxy)aluminate |
Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
---|---|---|---|---|---|---|---|---|---|
Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
AAA1329218
|
Thermo Scientific Chemicals
A1329218 |
50 g |
Each for $67.84
|
|
|||||
AAA1329230
|
Thermo Scientific Chemicals
A1329230 |
250 g |
Each for $120.44
|
|
|||||
AAA132920B
|
Thermo Scientific Chemicals
A132920B |
1000 g |
Each for $391.93
|
|
|||||
Description
Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsSodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines.
Solubility
Miscible with aromatic hydrocarbons, ether, tetrahydrofuran, dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons.
Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with water, oxidizing agents and combustible material.
Chemical Identifiers
22722-98-1 | |
C6H16AlNaO4 | |
MFCD00011631 | |
Sodium dihydrobis(2-methoxyethoxy)aluminate |
Specifications
22722-98-1 | |
4°C (39°F) | |
NaAlH2(OCH2CH2OCH3)2 | |
50 g | |
Moisture sensitive | |
Sodium dihydrobis(2-methoxyethoxy)aluminate | |
202.16 |
1.02 | |
C6H16AlNaO4 | |
MFCD00011631 | |
UN3399 | |
14,8565 | |
Miscible with aromatic hydrocarbons,ether,tetrahydrofuran,dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons. | |
Sodium bis(2-methoxyethoxy)aluminum hydride |
Safety and Handling
GHS H Statement
H225-H260-H304-H361-H373-H314-H332-H336
Highly flammable liquid and vapour.
In contact with water releases flammable gases which may ignite spontaneously.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes severe skin burns and eye damage.
Harmful if inhaled.
May cause drowsiness or dizziness.
P201-P202-P210-P233-P240-P241-P242-P243-P261-P262-P264b-P271-P280-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P330-P331-P363-P372-P374-P380-P501c
H225-H304-H314-H318-H361-H373-X
DOTInformation : Transport Hazard Class: 4.3; Packing Group: I; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
EINECSNumber : 245-178-2
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only