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Sodium bis(2-methoxyethoxy)aluminum hydride, 70% w/w in toluene.

CAS: 22722-98-1 | C6H16AlNaO4

Supplier:  Thermo Scientific Chemicals A1329230

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Catalog No. AAA1329230


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Description

Description

Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines.

Solubility
Miscible with aromatic hydrocarbons, ether, tetrahydrofuran, dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with water, oxidizing agents and combustible material.
Specifications

Specifications

Sodium bis(2-methoxyethoxy)aluminum hydride
1.02
C6H16AlNaO4
MFCD00011631
UN3399
14,8565
Miscible with aromatic hydrocarbons,ether,tetrahydrofuran,dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons.
22722-98-1
4°C (39°F)
NaAlH2(OCH2CH2OCH3)2
250 g
Moisture sensitive
Sodium dihydrobis(2-methoxyethoxy)aluminate
202.16

Chemical Identifiers

22722-98-1
C6H16AlNaO4
MFCD00011631
Sodium dihydrobis(2-methoxyethoxy)aluminate
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Safety and Handling

Safety and Handling

GHS H Statement
H225-H260-H304-H361-H373-H314-H332-H336
Highly flammable liquid and vapour.
In contact with water releases flammable gases which may ignite spontaneously.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes severe skin burns and eye damage.
Harmful if inhaled.
May cause drowsiness or dizziness.

P201-P202-P210-P233-P240-P241-P242-P243-P261-P262-P264b-P271-P280-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P330-P331-P363-P372-P374-P380-P501c

H225-H304-H314-H318-H361-H373-X

DOTInformation : Transport Hazard Class: 4.3; Packing Group: I; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE

EINECSNumber : 245-178-2

TSCA : Yes

Recommended Storage : Ambient temperatures

SDS
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