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Lithium acetylide ethylenediamine complex, tech. 85%, Thermo Scientific Chemicals

$186.90 - $549.92

Identifiants chimiques

CAS 6867-30-7
Molecular Formula C4H9LiN2
Molecular Weight (g/mol) 92.07
MDL Number MFCD00013183
InChI Key QJQWXTYPTBEPGS-UHFFFAOYSA-N
Synonym lithium acetylide ethylenediamine complex, lithium acetylide, ethylenediamine complex, lithium; ethane-1,2-diamine; ethyne, 1,2-ethanediamine compd. with lithium acetylide li c2h, lithium, 1,2-ethanediamine-kn1,kn2 ethynyl, 1,2-ethanediamine, compd. with lithium acetylide li c2h 1:?, c2h8n2.c2hli, lithium acetylide, compd. with 1,2-ethanediamine, lithium acetylide, ethylene diamine complex 1:1, lithium acetylide, compound with ethane-1,2-diamine
PubChem CID 2724010
IUPAC Name lithium;ethane-1,2-diamine;ethyne
SMILES [Li]C#C.NCCN
voir les spécifications

Produits 2
Numéro de catalogue Numéro du manufacturier. Quantity Prix Quantité  
Numéro de catalogue Numéro du manufacturier. Quantity Prix Quantité  
AAL1240114
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Thermo Scientific Chemicals
L1240114
25 g
chaque for $186.90
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AAL1240122
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Thermo Scientific Chemicals
L1240122
100 g
chaque for $549.92
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Description

Description

Lithium acetylide ethylenediamine complex is used in the synthesis of a chiral cyclopropanol. It is also used as an alkynylating reagent for the enantioselective alkynylation of ketones catalyzed by lithium binaphtholate without using other metal sources.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Lithium acetylide ethylenediamine complex is used in the synthesis of a chiral cyclopropanol. It is also used as an alkynylating reagent for the enantioselective alkynylation of ketones catalyzed by lithium binaphtholate without using other metal sources.

Solubility
Soluble in ethylene diamine, n-propyl amine, n-butyl amine, pyridine, dimethyl formamaide, diglyme, dioxan and dimethylsulfoxide.

Notes
Moisture and light sensitive. Store in cool place. Incompatible with alcohols, acids, oxidizing agents, water. It reacts with water to form lithium hydroxide and acetylene, which is a flammable gas. Over time, pressure may increase causing containers to burst. Handle and open container with care.
Spécifications

Identifiants chimiques

6867-30-7
92.07
QJQWXTYPTBEPGS-UHFFFAOYSA-N
2724010
[Li]C#C.NCCN
C4H9LiN2
MFCD00013183
lithium acetylide ethylenediamine complex, lithium acetylide, ethylenediamine complex, lithium; ethane-1,2-diamine; ethyne, 1,2-ethanediamine compd. with lithium acetylide li c2h, lithium, 1,2-ethanediamine-kn1,kn2 ethynyl, 1,2-ethanediamine, compd. with lithium acetylide li c2h 1:?, c2h8n2.c2hli, lithium acetylide, compd. with 1,2-ethanediamine, lithium acetylide, ethylene diamine complex 1:1, lithium acetylide, compound with ethane-1,2-diamine
lithium;ethane-1,2-diamine;ethyne

Spécifications

6867-30-7
1.04
C4H9LiN2
MFCD00013183
UN3131
Moisture sensitive
Soluble in ethylene diamine,n-propyl amine,n-butyl amine,pyridine,dimethyl formamaide,diglyme,dioxan and dimethylsulfoxide.
[Li]C#C.NCCN
92.07
92.07
Technical
∽76°C (decomposition)
Amine-like
HC≡CLi·NH2CH2CH2NH2
25 g
3593824
lithium acetylide ethylenediamine complex, lithium acetylide, ethylenediamine complex, lithium; ethane-1,2-diamine; ethyne, 1,2-ethanediamine compd. with lithium acetylide li c2h, lithium, 1,2-ethanediamine-kn1,kn2 ethynyl, 1,2-ethanediamine, compd. with lithium acetylide li c2h 1:?, c2h8n2.c2hli, lithium acetylide, compd. with 1,2-ethanediamine, lithium acetylide, ethylene diamine complex 1:1, lithium acetylide, compound with ethane-1,2-diamine
QJQWXTYPTBEPGS-UHFFFAOYSA-N
lithium;ethane-1,2-diamine;ethyne
2724010
90%
Lithium acetylide ethylenediamine complex
Videos
Sécurité et manipulation

Sécurité et manipulation

GHS H Statement
H261-H314-H318
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes serious eye damage.

P223-P231+P232-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378q-P501c

H260-H302-H314-H335

missing translation for 'dotInformation' : Transport Hazard Class: 4.3; Packing Group: I; Proper Shipping Name: WATER-REACTIVE SOLID, CORROSIVE, N.O.S.

missing translation for 'einecsNumber' : 229-967-9

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures

FDS
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RUO – Research Use Only