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Isopropyltriphenylphosphonium iodide, 98+%

CAS: 24470-78-8 | C21H22IP | 432.29 g/mol

$78.73 - $1039.77

Chemical Identifiers

CAS 24470-78-8
Molecular Formula C21H22IP
Molecular Weight (g/mol) 432.29
MDL Number MFCD00031595
InChI Key HHBXWXJLQYJJBW-UHFFFAOYSA-M
Synonym isopropyltriphenylphosphonium iodide, phosphonium, 1-methylethyl triphenyl-, iodide, isopropyltriphenylphosphanium iodide, isopropyl triphenyl phosphonium iodide, triphenyl propan-2-yl phosphanium iodide, i-propyl triphenylphosphonium iodide, isopropyl triphenylphosphonium iodide, acmc-209gck, ksc493k7j, isopropyltriphenylphosphine iodide
PubChem CID 2723783
IUPAC Name triphenyl(propan-2-yl)phosphanium;iodide
SMILES [I-].CC(C)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
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AAA1288109
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Thermo Scientific Chemicals
A1288109
10 g
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AAA1288122
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Thermo Scientific Chemicals
A1288122
100 g
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AAA1288130
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Thermo Scientific Chemicals
A1288130
250 g
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Description

Description

Useful precursor of isopropylidene unit by Wittig reaction with aldehydes. It is also used in tandem cyclopropanation and Wittig olefination in a synthesis of chrysanthemic acid. Also employed in Wittig and cyclopropanation reactions. It is used as a reactant for total synthesis of heliananes, in the preparation of highly substituted benzene derivatives, synthesis of curcuphenol and elvirol analogs via a retro-aldol reaction as fungicidal agents, 4-substituted methoxylbenzoyl-aryl-thiazoles analogues as potent and orally bioavailable anticancer agents.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Useful precursor of isopropylidene unit by Wittig reaction with aldehydes. It is also used in tandem cyclopropanation and Wittig olefination in a synthesis of chrysanthemic acid. Also employed in Wittig and cyclopropanation reactions. It is used as a reactant for total synthesis of heliananes, in the preparation of highly substituted benzene derivatives, synthesis of curcuphenol and elvirol analogs via a retro-aldol reaction as fungicidal agents, 4-substituted methoxylbenzoyl-aryl-thiazoles analogues as potent and orally bioavailable anticancer agents.

Solubility
Solubility in methanol, very faint turbidity.

Notes
Light sensitive and hygroscopic. Store away from oxidizing agents and light. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
Specifications

Chemical Identifiers

24470-78-8
432.29
HHBXWXJLQYJJBW-UHFFFAOYSA-M
2723783
[I-].CC(C)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
C21H22IP
MFCD00031595
isopropyltriphenylphosphonium iodide, phosphonium, 1-methylethyl triphenyl-, iodide, isopropyltriphenylphosphanium iodide, isopropyl triphenyl phosphonium iodide, triphenyl propan-2-yl phosphanium iodide, i-propyl triphenylphosphonium iodide, isopropyl triphenylphosphonium iodide, acmc-209gck, ksc493k7j, isopropyltriphenylphosphine iodide
triphenyl(propan-2-yl)phosphanium;iodide

Specifications

24470-78-8
C21H22IP
10 g
Hygroscopic; Light sensitive
HHBXWXJLQYJJBW-UHFFFAOYSA-M
triphenyl(propan-2-yl)phosphanium;iodide
2723783
≥98%
195°C to 198°C
MFCD00031595
3599629
isopropyltriphenylphosphonium iodide, phosphonium, 1-methylethyl triphenyl-, iodide, isopropyltriphenylphosphanium iodide, isopropyl triphenyl phosphonium iodide, triphenyl propan-2-yl phosphanium iodide, i-propyl triphenylphosphonium iodide, isopropyl triphenylphosphonium iodide, acmc-209gck, ksc493k7j, isopropyltriphenylphosphine iodide
[I-].CC(C)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
432.29
432.29
Isopropyltriphenylphosphonium iodide
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Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P271-P280-P302+P352-P305+P351+P338-P314-P332+P313-P362-P501c

H315-H319-H335

EINECSNumber : 246-281-5

TSCA : No

Recommended Storage : Ambient temperatures

SDS
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RUO – Research Use Only