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Isopropyltriphenylphosphonium iodide, 98+%
CAS: 24470-78-8 | C21H22IP | 432.29 g/mol
Supplier: Thermo Scientific Chemicals A1288130
Description
Useful precursor of isopropylidene unit by Wittig reaction with aldehydes. It is also used in tandem cyclopropanation and Wittig olefination in a synthesis of chrysanthemic acid. Also employed in Wittig and cyclopropanation reactions. It is used as a reactant for total synthesis of heliananes, in the preparation of highly substituted benzene derivatives, synthesis of curcuphenol and elvirol analogs via a retro-aldol reaction as fungicidal agents, 4-substituted methoxylbenzoyl-aryl-thiazoles analogues as potent and orally bioavailable anticancer agents.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsUseful precursor of isopropylidene unit by Wittig reaction with aldehydes. It is also used in tandem cyclopropanation and Wittig olefination in a synthesis of chrysanthemic acid. Also employed in Wittig and cyclopropanation reactions. It is used as a reactant for total synthesis of heliananes, in the preparation of highly substituted benzene derivatives, synthesis of curcuphenol and elvirol analogs via a retro-aldol reaction as fungicidal agents, 4-substituted methoxylbenzoyl-aryl-thiazoles analogues as potent and orally bioavailable anticancer agents.
Solubility
Solubility in methanol, very faint turbidity.
Notes
Light sensitive and hygroscopic. Store away from oxidizing agents and light. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
Specifications
| Isopropyltriphenylphosphonium iodide | |
| 195°C to 198°C | |
| MFCD00031595 | |
| 3599629 | |
| isopropyltriphenylphosphonium iodide, phosphonium, 1-methylethyl triphenyl-, iodide, isopropyltriphenylphosphanium iodide, isopropyl triphenyl phosphonium iodide, triphenyl propan-2-yl phosphanium iodide, i-propyl triphenylphosphonium iodide, isopropyl triphenylphosphonium iodide, acmc-209gck, ksc493k7j, isopropyltriphenylphosphine iodide | |
| [I-].CC(C)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 | |
| 432.29 | |
| 432.29 |
| 24470-78-8 | |
| C21H22IP | |
| 250 g | |
| Hygroscopic; Light sensitive | |
| HHBXWXJLQYJJBW-UHFFFAOYSA-M | |
| triphenyl(propan-2-yl)phosphanium;iodide | |
| 2723783 | |
| ≥98% |
Chemical Identifiers
| 24470-78-8 | |
| 432.29 | |
| HHBXWXJLQYJJBW-UHFFFAOYSA-M | |
| 2723783 | |
| [I-].CC(C)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 |
| C21H22IP | |
| MFCD00031595 | |
| isopropyltriphenylphosphonium iodide, phosphonium, 1-methylethyl triphenyl-, iodide, isopropyltriphenylphosphanium iodide, isopropyl triphenyl phosphonium iodide, triphenyl propan-2-yl phosphanium iodide, i-propyl triphenylphosphonium iodide, isopropyl triphenylphosphonium iodide, acmc-209gck, ksc493k7j, isopropyltriphenylphosphine iodide | |
| triphenyl(propan-2-yl)phosphanium;iodide |
Safety and Handling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P271-P280-P302+P352-P305+P351+P338-P314-P332+P313-P362-P501c
H315-H319-H335
EINECSNumber : 246-281-5
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only