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Bis(cyclopentadienyl)titanium dichloride, 97%
CAS: 1271-19-8 | C10H10Cl2Ti-2 | 248.957 g/mol
$84.48 - $918.10
Chemical Identifiers
| CAS | 1271-19-8 |
|---|---|
| Molecular Formula | C10H10Cl2Ti-2 |
| Molecular Weight (g/mol) | 248.957 |
| MDL Number | MFCD00003723 |
| InChI Key | MKNXBRLZBFVUPV-UHFFFAOYSA-L |
| Synonym | Dichlorobis(cyclopentadienyl)titanium; Titanocene dichloride |
| PubChem CID | 124040768 |
| IUPAC Name | cyclopenta-1,3-diene;titanium(2+);dichloride |
| SMILES | [CH-]1C=CC=C1.[CH-]1C=CC=C1.[Cl-].[Cl-].[Ti+2] |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAA1145609
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Thermo Scientific Chemicals
A1145609 |
10 g |
Each for $84.48
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AAA1145618
|
Thermo Scientific Chemicals
A1145618 |
50 g |
Each for $255.92
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AAA1145630
|
Thermo Scientific Chemicals
A1145630 |
250 g |
Each for $918.10
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Description
One-pot synthesis of α-methylene-γ-butyrolactones from benzaldehydes and bromomethylacrylates. Bis-(cyclopentadienyl)-titanium dichloride alkylaluminum complexls acts as catalysts for the polymerization of ethylene. Polyethylene prepared with these catalysts. Complexes of aluminum chloride and methylaluminum dichloride with bis-(cyclopentadienyl)-titanium dichloride as catalysts for the polymerization of ethylene.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsOne-pot synthesis of α-methylene-γ-butyrolactones from benzaldehydes and bromomethylacrylates. Bis-(cyclopentadienyl)-titanium dichloride alkylaluminum complexls acts as catalysts for the polymerization of ethylene. Polyethylene prepared with these catalysts. Complexes of aluminum chloride and methylaluminum dichloride with bis-(cyclopentadienyl)-titanium dichloride as catalysts for the polymerization of ethylene.
Solubility
Slightly soluble in water
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, moisture, water, air.
Chemical Identifiers
| 1271-19-8 | |
| 248.957 | |
| MKNXBRLZBFVUPV-UHFFFAOYSA-L | |
| 124040768 | |
| [CH-]1C=CC=C1.[CH-]1C=CC=C1.[Cl-].[Cl-].[Ti+2] |
| C10H10Cl2Ti-2 | |
| MFCD00003723 | |
| Dichlorobis(cyclopentadienyl)titanium; Titanocene dichloride | |
| cyclopenta-1,3-diene;titanium(2+);dichloride |
Specifications
| 1271-19-8 | |
| 1.6 | |
| C10H10Cl2Ti-2 | |
| 10 g | |
| 14,9482 | |
| Slightly soluble in water | |
| [CH-]1C=CC=C1.[CH-]1C=CC=C1.[Cl-].[Cl-].[Ti+2] | |
| 248.957 | |
| 249 | |
| Bis (cyclopentadienyl)titanium dichloride |
| ∼285°C (decomposition) | |
| Odorless | |
| MFCD00003723 | |
| Air and moisture sensitive | |
| Dichlorobis(cyclopentadienyl)titanium; Titanocene dichloride | |
| MKNXBRLZBFVUPV-UHFFFAOYSA-L | |
| cyclopenta-1,3-diene;titanium(2+);dichloride | |
| 124040768 | |
| 97% |
Safety and Handling
GHS H Statement
H341-H302-H332-H315-H319-H335
Suspected of causing genetic defects.
Harmful if swallowed.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
H315-H319-H335
EINECSNumber : 215-035-9
RTECSNumber : XR2050000
TSCA : Yes
Recommended Storage : Ambient temperatures; Store under Argon
RUO – Research Use Only