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Bis(cyclopentadienyl)titanium dichloride, 97%

CAS: 1271-19-8 | C10H10Cl2Ti-2 | 248.957 g/mol

Supplier:  Thermo Scientific Chemicals A1145618

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Catalog No. AAA1145618

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Description

Description

One-pot synthesis of α-methylene-γ-butyrolactones from benzaldehydes and bromomethylacrylates. Bis-(cyclopentadienyl)-titanium dichloride alkylaluminum complexls acts as catalysts for the polymerization of ethylene. Polyethylene prepared with these catalysts. Complexes of aluminum chloride and methylaluminum dichloride with bis-(cyclopentadienyl)-titanium dichloride as catalysts for the polymerization of ethylene.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
One-pot synthesis of α-methylene-γ-butyrolactones from benzaldehydes and bromomethylacrylates. Bis-(cyclopentadienyl)-titanium dichloride alkylaluminum complexls acts as catalysts for the polymerization of ethylene. Polyethylene prepared with these catalysts. Complexes of aluminum chloride and methylaluminum dichloride with bis-(cyclopentadienyl)-titanium dichloride as catalysts for the polymerization of ethylene.

Solubility
Slightly soluble in water

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, moisture, water, air.
Specifications

Specifications

Bis (cyclopentadienyl)titanium dichloride
∼285°C (decomposition)
Odorless
MFCD00003723
Air and moisture sensitive
Dichlorobis(cyclopentadienyl)titanium; Titanocene dichloride
MKNXBRLZBFVUPV-UHFFFAOYSA-L
cyclopenta-1,3-diene;titanium(2+);dichloride
124040768
97%
1271-19-8
1.6
C10H10Cl2Ti-2
50 g
14,9482
Slightly soluble in water
[CH-]1C=CC=C1.[CH-]1C=CC=C1.[Cl-].[Cl-].[Ti+2]
248.957
249

Chemical Identifiers

1271-19-8
248.957
MKNXBRLZBFVUPV-UHFFFAOYSA-L
124040768
[CH-]1C=CC=C1.[CH-]1C=CC=C1.[Cl-].[Cl-].[Ti+2]
C10H10Cl2Ti-2
MFCD00003723
Dichlorobis(cyclopentadienyl)titanium; Titanocene dichloride
cyclopenta-1,3-diene;titanium(2+);dichloride
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Safety and Handling

Safety and Handling

GHS H Statement
H341-H302-H332-H315-H319-H335
Suspected of causing genetic defects.
Harmful if swallowed.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

EINECSNumber : 215-035-9

RTECSNumber : XR2050000

TSCA : Yes

Recommended Storage : Ambient temperatures; Store under Argon

SDS
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