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Trichloroacetonitrile, 98%

CAS: 545-06-2 | C2Cl3N | 144.379 g/mol

Supplier:  Thermo Scientific Chemicals A1056518

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Catalog No. AAA1056518


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Description

Description

Trichloroacetonitrile is involved as a reagent in Overman rearrangement, which is used to prepare alylic amines from allylic alcohols. It is also used to prepare bistrichloroacetimidates from diols leading to dihyrooxazines through acid catalyzed cyclization. Further, it is utilized in the synthesis of trichloroacetimidates by 1,8-Diazobicyclo[5.4.0]undec-7-ene (DBU) catalyzed addition of allylic alcohols. It finds application in the study of the methoxy methyl (MOM) catalyzed aza-Claisen rearrangement.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Trichloroacetonitrile is involved as a reagent in Overman rearrangement, which is used to prepare alylic amines from allylic alcohols. It is also used to prepare bistrichloroacetimidates from diols leading to dihyrooxazines through acid catalyzed cyclization. Further, it is utilized in the synthesis of trichloroacetimidates by 1,8-Diazobicyclo[5.4.0]undec-7-ene (DBU) catalyzed addition of allylic alcohols. It finds application in the study of the methoxy methyl (MOM) catalyzed aza-Claisen rearrangement.

Solubility
Miscible with most organic solvents. Immiscible with water.

Notes
Incompatible with strong acids, strong bases, strong oxidizing agents and strong reducing agents.
Specifications

Specifications

Trichloroacetonitrile
-44°C
85°C to 86°C
C2Cl3N
Cl3CCN
50 g
605572
trichloroacetonitrile, acetonitrile, trichloro, tritox, cyanotrichloromethane, trichloromethyl cyanide, trichloroethanenitrile, trichlouracetonitril, trichlor-acetonitrile, trichloromethylnitrile, nitrile trichloracetique
DRUIESSIVFYOMK-UHFFFAOYSA-N
2,2,2-trichloroacetonitrile
11011
144.39
545-06-2
1.44
98%
1.441
MFCD00001842
UN3276
14,9628
Miscible with most organic solvents. Immiscible with water.
C(#N)C(Cl)(Cl)Cl
144.379
CHEBI:82541
98%

Chemical Identifiers

545-06-2
144.379
DRUIESSIVFYOMK-UHFFFAOYSA-N
11011
2,2,2-trichloroacetonitrile
C2Cl3N
MFCD00001842
trichloroacetonitrile, acetonitrile, trichloro, tritox, cyanotrichloromethane, trichloromethyl cyanide, trichloroethanenitrile, trichlouracetonitril, trichlor-acetonitrile, trichloromethylnitrile, nitrile trichloracetique
CHEBI:82541
C(#N)C(Cl)(Cl)Cl
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Safety and Handling

Safety and Handling

GHS H Statement
H301-H311-H331
Toxic if swallowed.
Toxic in contact with skin.
Toxic if inhaled.

P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P311-P312-P330-P361-P363-P501c

H301+H311+H331

DOTInformation : Hazard Class: 6.1; Packaging Group: II

EINECSNumber : 208-885-7

RTECSNumber : AM2450000

TSCA : Yes

Recommended Storage : Ambient temperatures

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