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trans-Dichlorobis(triphenylphosphine)palladium(II), Pd 14.0% min
Hydrogenation, hydrosilation, carbonylation, oxidation, and C-C bond formation | CAS: 13965-03-2 | C36H30Cl2P2Pd | 701.90 g/mol
$88.75 - $443.84
Chemical Identifiers
| CAS | 13965-03-2 |
|---|---|
| Molecular Formula | C36H30Cl2P2Pd |
| Molecular Weight (g/mol) | 701.90 |
| MDL Number | MFCD00009593 |
| InChI Key | YNHIGQDRGKUECZ-UHFFFAOYSA-L |
| Synonym | bis triphenylphosphine palladium ii dichloride, bis triphenylphosphine palladium ii chloride, dichlorobis triphenylphosphine palladium, bis triphenylphosphine palladium chloride, bis triphenylphosphine palladiuml ii dichloride, palladium 2+ ; triphenylphosphane; dichloride, trans-dichlorobis triphenylphosphine palladium ii 1g |
| PubChem CID | 131664180 |
| IUPAC Name | ethane;methane;palladium(2+);triphenylphosphane;dichloride |
| SMILES | [Cl-].[Cl-].[Pd++].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1 |
Description
As a catalyst of choice in hydrogenation, hydrosilation, carbonylation, oxidation, elimination, reduction, allyl aceate isomerization, dimerization of 1,3-dienes, and C-C bond formation such as Negishi coupling, Suzuki coupling, Kumada coupling, Sonogashira coupling, Heck coupling and Sonogashira-Hagihara coupling reactions. Used in the preparation of tetrakis(triphenylphosphine)palladium, condensed heterocycles such as furoquinolines, diphenylacetylenes, and several other compounds.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Chemical Identifiers
| 13965-03-2 | |
| 701.90 | |
| YNHIGQDRGKUECZ-UHFFFAOYSA-L | |
| 131664180 | |
| [Cl-].[Cl-].[Pd++].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1 |
| C36H30Cl2P2Pd | |
| MFCD00009593 | |
| bis triphenylphosphine palladium ii dichloride, bis triphenylphosphine palladium ii chloride, dichlorobis triphenylphosphine palladium, bis triphenylphosphine palladium chloride, bis triphenylphosphine palladiuml ii dichloride, palladium 2+ ; triphenylphosphane; dichloride, trans-dichlorobis triphenylphosphine palladium ii 1g | |
| ethane;methane;palladium(2+);triphenylphosphane;dichloride |
Specifications
| 13965-03-2 | |
| Yellow | |
| C36H30Cl2P2Pd | |
| MFCD00009593 | |
| Hygroscopic | |
| Insoluble in water. Soluble in benzene,and toluene. | |
| [Cl-].[Cl-].[Pd++].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1 | |
| 701.90 | |
| 701.91 | |
| Crystalline |
| ∼310°C (decomposition) | |
| Odorless | |
| PdCl2[P(C6H5)3]2 | |
| 1 g | |
| bis triphenylphosphine palladium ii dichloride, bis triphenylphosphine palladium ii chloride, dichlorobis triphenylphosphine palladium, bis triphenylphosphine palladium chloride, bis triphenylphosphine palladiuml ii dichloride, palladium 2+ ; triphenylphosphane; dichloride, trans-dichlorobis triphenylphosphine palladium ii 1g | |
| YNHIGQDRGKUECZ-UHFFFAOYSA-L | |
| ethane;methane;palladium(2+);triphenylphosphane;dichloride | |
| 131664180 | |
| Pd 14.0% min. | |
| trans-Dichlorobis(triphenylphosphine)palladium(II) |
Safety and Handling
EINECSNumber : 237-744-2
RTECSNumber : RT3578000
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only