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(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 98%
CAS: 76189-55-4 | C44H32P2 | 622.69 g/mol
$63.00 - $774.92
Chemical Identifiers
| CAS | 76189-55-4 |
|---|---|
| Molecular Formula | C44H32P2 |
| Molecular Weight (g/mol) | 622.69 |
| MDL Number | MFCD00010805 |
| InChI Key | MUALRAIOVNYAIW-UHFFFAOYSA-N |
| Synonym | binap, r-+-2,2'-bis diphenylphosphino-1,1'-binaphthyl, 2,2'-bis diphenylphosphino-1,1'-binaphthyl, s-binap, s---binap, s---2,2'-bis diphenylphosphino-1,1'-binaphthyl, r-+-binap, r-binap, rac-binap, 2,2'-bis diphenylphosphino-1,1'-binaphthalene |
| PubChem CID | 634876 |
| SMILES | C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=C2C=CC=CC2=C1C1=C(C=CC2=CC=CC=C12)P(C1=CC=CC=C1)C1=CC=CC=C1 |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAB23785MD
|
Thermo Scientific Chemicals
B23785MD |
250 mg |
N/A
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AAB2378503
|
Thermo Scientific Chemicals
B2378503 |
1 g |
N/A
|
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AAB2378506
|
Thermo Scientific Chemicals
B2378506 |
5 g |
N/A
|
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Description
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthy is used as a chiral ligand for metal mediated asymmetric catalysis.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications(R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthy is used as a chiral ligand for metal mediated asymmetric catalysis.
Solubility
Insoluble in water.
Notes
Air sensitive. Incompatible with oxidizing agents.
Chemical Identifiers
| 76189-55-4 | |
| 622.69 | |
| MUALRAIOVNYAIW-UHFFFAOYSA-N | |
| 634876 |
| C44H32P2 | |
| MFCD00010805 | |
| binap, r-+-2,2'-bis diphenylphosphino-1,1'-binaphthyl, 2,2'-bis diphenylphosphino-1,1'-binaphthyl, s-binap, s---binap, s---2,2'-bis diphenylphosphino-1,1'-binaphthyl, r-+-binap, r-binap, rac-binap, 2,2'-bis diphenylphosphino-1,1'-binaphthalene | |
| C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=C2C=CC=CC2=C1C1=C(C=CC2=CC=CC=C12)P(C1=CC=CC=C1)C1=CC=CC=C1 |
Specifications
| 76189-55-4 | |
| C44H32P2 | |
| 250 mg | |
| 14,1223 | |
| MUALRAIOVNYAIW-UHFFFAOYSA-N | |
| C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=C2C=CC=CC2=C1C1=C(C=CC2=CC=CC=C12)P(C1=CC=CC=C1)C1=CC=CC=C1 | |
| 622.69 | |
| 622.69 | |
| (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl |
| 239°C to 241°C | |
| MFCD00010805 | |
| 4914063 | |
| binap, r-+-2,2'-bis diphenylphosphino-1,1'-binaphthyl, 2,2'-bis diphenylphosphino-1,1'-binaphthyl, s-binap, s---binap, s---2,2'-bis diphenylphosphino-1,1'-binaphthyl, r-+-binap, r-binap, rac-binap, 2,2'-bis diphenylphosphino-1,1'-binaphthalene | |
| +230° (c=0.3 in Toluene) | |
| [1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane | |
| 634876 | |
| 98% |
Safety and Handling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
H315-H319-H335
TSCA : No
Recommended Storage : Ambient temperatures; Store under Nitrogen
RUO – Research Use Only