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p-Toluenesulfonylmethyl isocyanide, 97%
CAS: 36635-61-7 | C9H9NO2S | 195.24 g/mol
Supplier: Thermo Scientific Chemicals A1431206
Description
p-Toluenesulfonylmethyl isocyanide is a synthetic reagent used in the synthesis of triplet drugs with the 1,3,5-trioxazatriquinane skeleton, pyrroles, oxazoles and in imidazoles. It serves as an isonitrile component in a diastereoselective Passerini reaction. Furthermore, it is used in the Van Leusen reaction to convert aldehydes to nitriles.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applicationsp-Toluenesulfonylmethyl isocyanide is a synthetic reagent used in the synthesis of triplet drugs with the 1,3,5-trioxazatriquinane skeleton, pyrroles, oxazoles and in imidazoles. It serves as an isonitrile component in a diastereoselective Passerini reaction. Furthermore, it is used in the Van Leusen reaction to convert aldehydes to nitriles.
Solubility
Soluble in chloroform and methanol. Insoluble in water.
Notes
Moisture, air and light sensitive. Store in cool place. Incompatible with strong bases and strong oxidizing agents.
Specifications
| p-Toluenesulfonylmethyl isocyanide | |
| 109°C to 114°C | |
| MFCD00000005 | |
| UN2811 | |
| Moisture sensitive | |
| Soluble in chloroform and methanol. Insoluble in water. | |
| CC1=CC=C(C=C1)S(=O)(=O)C[N+]#[C-] | |
| 195.24 | |
| 195.24 |
| 36635-61-7 | |
| C9H9NO2S | |
| 5 g | |
| 3592382 | |
| tosylmethyl isocyanide, tosmic, p-toluenesulfonylmethyl isocyanide, 4-toluenesulphonylmethyl isocyanide, 4-toluenesulfonylmethyl isocyanide, tosylmethylisocyanide, 1-isocyanomethylsulfonyl-4-methylbenzene, p-tolylsulfonyl methyl isocyanide, unii-c35fd6olh8, 1-isocyanomethyl sulfonyl-4-methylbenzene | |
| CFOAUYCPAUGDFF-UHFFFAOYSA-N | |
| 1-(isocyanomethylsulfonyl)-4-methylbenzene | |
| 161915 | |
| ≥97% |
Chemical Identifiers
| 36635-61-7 | |
| 195.24 | |
| CFOAUYCPAUGDFF-UHFFFAOYSA-N | |
| 161915 | |
| CC1=CC=C(C=C1)S(=O)(=O)C[N+]#[C-] |
| C9H9NO2S | |
| MFCD00000005 | |
| tosylmethyl isocyanide, tosmic, p-toluenesulfonylmethyl isocyanide, 4-toluenesulphonylmethyl isocyanide, 4-toluenesulfonylmethyl isocyanide, tosylmethylisocyanide, 1-isocyanomethylsulfonyl-4-methylbenzene, p-tolylsulfonyl methyl isocyanide, unii-c35fd6olh8, 1-isocyanomethyl sulfonyl-4-methylbenzene | |
| 1-(isocyanomethylsulfonyl)-4-methylbenzene |
Safety and Handling
GHS H Statement
H300-H311-H331
Fatal if swallowed.
Toxic in contact with skin.
Toxic if inhaled.
P261-P264b-P270-P271-P280-P285-P301+P310-P302+P352-P304+P340-P311-P312-P330-P361-P363-P501c
H301+H311+H331-H334
DOTInformation : Transport Hazard Class: 6.1; Packing Group: II; Proper Shipping Name: TOXIC SOLIDS, ORGANIC, N.O.S.
EINECSNumber : 253-140-1
TSCA : No
Recommended Storage : Ambient temperatures; Store under Nitrogen
RUO – Research Use Only