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(N,N-Dimethyl)methyleneammonium iodide, 97%

CAS: 33797-51-2 | C3H8IN | 185.008 g/mol

$176.81 - $2705.96

Chemical Identifiers

CAS 33797-51-2
Molecular Formula C3H8IN
Molecular Weight (g/mol) 185.008
MDL Number MFCD00011810
InChI Key VVDUZZGYBOWDSQ-UHFFFAOYSA-M
Synonym eschenmoser's salt, n,n-dimethylmethyleneiminium iodide, n-methyl-n-methylenemethanaminium iodide, dimethyl methylidene azanium iodide, n,n-dimethyl methyleneammonium iodide, dimethyl methylene ammonium iodide, methanaminium, n-methyl-n-methylene-, iodide, eschenmoser inverted exclamation mark s salt, eschenmoser salt, dimethyl methylene ammounium iodide
PubChem CID 2724133
IUPAC Name dimethyl(methylidene)azanium;iodide
SMILES C[N+](=C)C.[I-]
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AAA1514609
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Thermo Scientific Chemicals
A1514609
10 g
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AAA1514618
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50 g
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AAA1514630
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A1514630
250 g
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Description

Description

(N,N-Dimethyl)methyleneammonium iodide is a useful reagent for many synthetic applications like aminomethylation. It is also essential for the conversion of ketones to α, β-unsaturated enones. It is utilized to prepare derivatives of the type RCH2N(CH3)2. It is extensively used in medicines like painkillers and sedatives- Tramadol hydrochloride intermediate viz. 2-dimethylamine methylcyclohexanone. It is also employed in reactive dyes, synthesized spices. It plays an essential role in Mannich reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(N,N-Dimethyl)methyleneammonium iodide is a useful reagent for many synthetic applications like aminomethylation. It is also essential for the conversion of ketones to α, β-unsaturated enones. It is utilized to prepare derivatives of the type RCH2N(CH3)2. It is extensively used in medicines like painkillers and sedatives- Tramadol hydrochloride intermediate viz. 2-dimethylamine methylcyclohexanone. It is also employed in reactive dyes, synthesized spices. It plays an essential role in Mannich reactions.

Solubility
Soluble in dimethylformamide. Partially soluble in acetonitrile, tetrahydrofuran and dichloromethane.

Notes
Moisture and light sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place.
Specifications

Chemical Identifiers

33797-51-2
185.008
VVDUZZGYBOWDSQ-UHFFFAOYSA-M
2724133
C[N+](=C)C.[I-]
C3H8IN
MFCD00011810
eschenmoser's salt, n,n-dimethylmethyleneiminium iodide, n-methyl-n-methylenemethanaminium iodide, dimethyl methylidene azanium iodide, n,n-dimethyl methyleneammonium iodide, dimethyl methylene ammonium iodide, methanaminium, n-methyl-n-methylene-, iodide, eschenmoser inverted exclamation mark s salt, eschenmoser salt, dimethyl methylene ammounium iodide
dimethyl(methylidene)azanium;iodide

Specifications

33797-51-2
C3H8IN
10 g
Light and moisture sensitive
eschenmoser's salt, n,n-dimethylmethyleneiminium iodide, n-methyl-n-methylenemethanaminium iodide, dimethyl methylidene azanium iodide, n,n-dimethyl methyleneammonium iodide, dimethyl methylene ammonium iodide, methanaminium, n-methyl-n-methylene-, iodide, eschenmoser inverted exclamation mark s salt, eschenmoser salt, dimethyl methylene ammounium iodide
VVDUZZGYBOWDSQ-UHFFFAOYSA-M
dimethyl(methylidene)azanium;iodide
2724133
97%
∼240°C (decomposition)
MFCD00011810
3594966
14,3251
Soluble in dimethylformamide. Partially soluble in acetonitrile,tetrahydrofuran and dichloromethane.
C[N+](=C)C.[I-]
185.008
185.01
(N,N-Dimethyl)methyleneammonium iodide
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Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

EINECSNumber : 251-680-2

TSCA : No

Recommended Storage : Keep cold

SDS
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RUO – Research Use Only