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(N,N-Dimethyl)methyleneammonium iodide, 97%
CAS: 33797-51-2 | C3H8IN | 185.008 g/mol
$176.81 - $2705.96
Chemical Identifiers
CAS | 33797-51-2 |
---|---|
Molecular Formula | C3H8IN |
Molecular Weight (g/mol) | 185.008 |
MDL Number | MFCD00011810 |
InChI Key | VVDUZZGYBOWDSQ-UHFFFAOYSA-M |
Synonym | eschenmoser's salt, n,n-dimethylmethyleneiminium iodide, n-methyl-n-methylenemethanaminium iodide, dimethyl methylidene azanium iodide, n,n-dimethyl methyleneammonium iodide, dimethyl methylene ammonium iodide, methanaminium, n-methyl-n-methylene-, iodide, eschenmoser inverted exclamation mark s salt, eschenmoser salt, dimethyl methylene ammounium iodide |
PubChem CID | 2724133 |
IUPAC Name | dimethyl(methylidene)azanium;iodide |
SMILES | C[N+](=C)C.[I-] |
Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
AAA1514609
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Thermo Scientific Chemicals
A1514609 |
10 g |
Each for $176.81
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AAA1514618
|
Thermo Scientific Chemicals
A1514618 |
50 g |
Each for $572.68
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AAA1514630
|
Thermo Scientific Chemicals
A1514630 |
250 g |
Each for $2,705.96
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Description
(N,N-Dimethyl)methyleneammonium iodide is a useful reagent for many synthetic applications like aminomethylation. It is also essential for the conversion of ketones to α, β-unsaturated enones. It is utilized to prepare derivatives of the type RCH2N(CH3)2. It is extensively used in medicines like painkillers and sedatives- Tramadol hydrochloride intermediate viz. 2-dimethylamine methylcyclohexanone. It is also employed in reactive dyes, synthesized spices. It plays an essential role in Mannich reactions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications(N,N-Dimethyl)methyleneammonium iodide is a useful reagent for many synthetic applications like aminomethylation. It is also essential for the conversion of ketones to α, β-unsaturated enones. It is utilized to prepare derivatives of the type RCH2N(CH3)2. It is extensively used in medicines like painkillers and sedatives- Tramadol hydrochloride intermediate viz. 2-dimethylamine methylcyclohexanone. It is also employed in reactive dyes, synthesized spices. It plays an essential role in Mannich reactions.
Solubility
Soluble in dimethylformamide. Partially soluble in acetonitrile, tetrahydrofuran and dichloromethane.
Notes
Moisture and light sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place.
Chemical Identifiers
33797-51-2 | |
185.008 | |
VVDUZZGYBOWDSQ-UHFFFAOYSA-M | |
2724133 | |
C[N+](=C)C.[I-] |
C3H8IN | |
MFCD00011810 | |
eschenmoser's salt, n,n-dimethylmethyleneiminium iodide, n-methyl-n-methylenemethanaminium iodide, dimethyl methylidene azanium iodide, n,n-dimethyl methyleneammonium iodide, dimethyl methylene ammonium iodide, methanaminium, n-methyl-n-methylene-, iodide, eschenmoser inverted exclamation mark s salt, eschenmoser salt, dimethyl methylene ammounium iodide | |
dimethyl(methylidene)azanium;iodide |
Specifications
33797-51-2 | |
C3H8IN | |
10 g | |
Light and moisture sensitive | |
eschenmoser's salt, n,n-dimethylmethyleneiminium iodide, n-methyl-n-methylenemethanaminium iodide, dimethyl methylidene azanium iodide, n,n-dimethyl methyleneammonium iodide, dimethyl methylene ammonium iodide, methanaminium, n-methyl-n-methylene-, iodide, eschenmoser inverted exclamation mark s salt, eschenmoser salt, dimethyl methylene ammounium iodide | |
VVDUZZGYBOWDSQ-UHFFFAOYSA-M | |
dimethyl(methylidene)azanium;iodide | |
2724133 | |
97% |
∼240°C (decomposition) | |
MFCD00011810 | |
3594966 | |
14,3251 | |
Soluble in dimethylformamide. Partially soluble in acetonitrile,tetrahydrofuran and dichloromethane. | |
C[N+](=C)C.[I-] | |
185.008 | |
185.01 | |
(N,N-Dimethyl)methyleneammonium iodide |
Safety and Handling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
H315-H319-H335
EINECSNumber : 251-680-2
TSCA : No
Recommended Storage : Keep cold
RUO – Research Use Only