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(Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+%

CAS: 1779-58-4 | C21H20BrO2P | 415.27 g/mol

Supplier:  Thermo Scientific Chemicals A1630122

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Catalog No. AAA1630122


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Description

Description

(Methoxycarbonylmethyl)triphenylphosphonium bromide is a reactant for the synthesis of GSK-3 inhibitors using the Wittig reaction, substituted furanones for antifungal and cytostatic activities, photochromic dithienylethene derivatives, gem-diiodoalkanes containing allylic alcohols and highly substituted cyclopentenes and brazilanes via Au-catalyzed deoxygenative Nazarov cyclization. As reactant for asymmetric hydrogenation of α,β-unsaturated ester-phosphonates, studies of thermal decomposition of phosphonium alkyl ester salts.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(Methoxycarbonylmethyl)triphenylphosphonium bromide is a reactant for the synthesis of GSK-3 inhibitors using the Wittig reaction, substituted furanones for antifungal and cytostatic activities, photochromic dithienylethene derivatives, gem-diiodoalkanes containing allylic alcohols and highly substituted cyclopentenes and brazilanes via Au-catalyzed deoxygenative Nazarov cyclization. As reactant for asymmetric hydrogenation of α,β-unsaturated ester-phosphonates, studies of thermal decomposition of phosphonium alkyl ester salts.

Solubility
Soluble in methanol(almost transparency).

Notes
Hygroscopic. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture.
Specifications

Specifications

(Methoxycarbonylmethyl)triphenylphosphonium bromide
∼163°C (decomposition)
MFCD00011801
3812975
2-methoxy-2-oxoethyl triphenylphosphonium bromide, methoxycarbonylmethyl triphenylphosphonium bromide, carbomethoxymethyl triphenylphosphonium bromide, methoxycarbonylmethyl triphenyl phosphonium bromide, 2-methoxy-2-oxoethyl triphenylphosphanium bromide, 2-methoxy-2-oxoethyl-triphenylphosphanium bromide, 2-methoxy-2-oxo-ethyl-triphenyl-phosphonium bromide, phosphonium, 2-methoxy-2-oxoethyl triphenyl-, bromide, acmc-209edx
VCWBQLMDSMSVRL-UHFFFAOYSA-M
(2-methoxy-2-oxoethyl)-triphenylphosphanium;bromide
2733211
≥98%
1779-58-4
C21H20BrO2P
100 g
Hygroscopic
Soluble in methanol(almost transparency).
[Br-].COC(=O)C[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
415.27
415.28

Chemical Identifiers

1779-58-4
415.27
VCWBQLMDSMSVRL-UHFFFAOYSA-M
2733211
[Br-].COC(=O)C[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
C21H20BrO2P
MFCD00011801
2-methoxy-2-oxoethyl triphenylphosphonium bromide, methoxycarbonylmethyl triphenylphosphonium bromide, carbomethoxymethyl triphenylphosphonium bromide, methoxycarbonylmethyl triphenyl phosphonium bromide, 2-methoxy-2-oxoethyl triphenylphosphanium bromide, 2-methoxy-2-oxoethyl-triphenylphosphanium bromide, 2-methoxy-2-oxo-ethyl-triphenyl-phosphonium bromide, phosphonium, 2-methoxy-2-oxoethyl triphenyl-, bromide, acmc-209edx
(2-methoxy-2-oxoethyl)-triphenylphosphanium;bromide
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Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

EINECSNumber : 217-222-0

TSCA : No

Recommended Storage : Ambient temperatures

SDS
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