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Magnesium bromide diethyl etherate, 98%

CAS: 29858-07-9 | C4H10Br2MgO | 258.24 g/mol

Supplier:  Thermo Scientific Chemicals L1548114

Catalog No. AAL1548114


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Description

Description

The magnesium bromide diethyl etherate (MgBr2· OEt2)-methyl sulfide (Me2S) system is useful for the mild and chemo-selective deprotection of p-methoxybenzyl (PMB) ether. Lewis acid for catalysis of Diels-Alder reactions of homochiral 2-sulfinylmaleates with cyclopentadiene. Magnesium bromide diethyl etherate is used in the synthesis of silicon-containing azole derivatives.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
The magnesium bromide diethyl etherate (MgBr2· OEt2)-methyl sulfide (Me2S) system is useful for the mild and chemo-selective deprotection of p-methoxybenzyl (PMB) ether. Lewis acid for catalysis of Diels-Alder reactions of homochiral 2-sulfinylmaleates with cyclopentadiene. Magnesium bromide diethyl etherate is used in the synthesis of silicon-containing azole derivatives.

Solubility
Hydrolyzes in water.

Notes
Moisture sensitive.Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, moisture.
Specifications

Specifications

Magnesium bromide diethyl etherate
35°C (95°F)
(CH3CH2)2O·MgBr2
25 g
Moisture sensitive
Hydrolyzes in water.
Br[Mg]Br.CCOCC
258.24
258.24
29858-07-9
C4H10Br2MgO
MFCD00064500
UN1325
magnesium bromide diethyl etherate, magnesium bromide etherate, magnesium bromide ethyl etherate, grignard reagent
JGZKUKYUQJUUNE-UHFFFAOYSA-L
magnesium;ethoxyethane;dibromide
11010650
98%
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Safety and Handling

Safety and Handling

GHS H Statement
H228
Flammable solid.

P210-P240-P241-P280-P370+P378q

H228-H500

DOTInformation : Transport Hazard Class: 4.1; Packing Group: II; Proper Shipping Name: FLAMMABLE SOLIDS, ORGANIC, N.O.S.

TSCA : No

Recommended Storage : Ambient temperatures

SDS
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