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Magnesium bromide diethyl etherate, 98%
CAS: 29858-07-9 | C4H10Br2MgO | 258.24 g/mol
Supplier: Thermo Scientific Chemicals L1548114
Description
The magnesium bromide diethyl etherate (MgBr2· OEt2)-methyl sulfide (Me2S) system is useful for the mild and chemo-selective deprotection of p-methoxybenzyl (PMB) ether. Lewis acid for catalysis of Diels-Alder reactions of homochiral 2-sulfinylmaleates with cyclopentadiene. Magnesium bromide diethyl etherate is used in the synthesis of silicon-containing azole derivatives.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsThe magnesium bromide diethyl etherate (MgBr2· OEt2)-methyl sulfide (Me2S) system is useful for the mild and chemo-selective deprotection of p-methoxybenzyl (PMB) ether. Lewis acid for catalysis of Diels-Alder reactions of homochiral 2-sulfinylmaleates with cyclopentadiene. Magnesium bromide diethyl etherate is used in the synthesis of silicon-containing azole derivatives.
Solubility
Hydrolyzes in water.
Notes
Moisture sensitive.Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, moisture.
Specifications
Magnesium bromide diethyl etherate | |
35°C (95°F) | |
(CH3CH2)2O·MgBr2 | |
25 g | |
Moisture sensitive | |
Hydrolyzes in water. | |
Br[Mg]Br.CCOCC | |
258.24 | |
258.24 |
29858-07-9 | |
C4H10Br2MgO | |
MFCD00064500 | |
UN1325 | |
magnesium bromide diethyl etherate, magnesium bromide etherate, magnesium bromide ethyl etherate, grignard reagent | |
JGZKUKYUQJUUNE-UHFFFAOYSA-L | |
magnesium;ethoxyethane;dibromide | |
11010650 | |
98% |
Safety and Handling
GHS H Statement
H228
Flammable solid.
P210-P240-P241-P280-P370+P378q
H228-H500
DOTInformation : Transport Hazard Class: 4.1; Packing Group: II; Proper Shipping Name: FLAMMABLE SOLIDS, ORGANIC, N.O.S.
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only