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m-Anisidine, 98%
CAS: 536-90-3 | C7H9NO | 123.155 g/mol
$76.05 - $685.44
Chemical Identifiers
| CAS | 536-90-3 |
|---|---|
| Molecular Formula | C7H9NO |
| Molecular Weight (g/mol) | 123.155 |
| MDL Number | MFCD00007783 |
| InChI Key | NCBZRJODKRCREW-UHFFFAOYSA-N |
| Synonym | m-anisidine, 3-aminoanisole, m-methoxyaniline, 3-methoxybenzenamine, 3-anisidine, m-aminoanisole, benzenamine, 3-methoxy, m-anisylamine, 1-amino-3-methoxybenzene, unii-jxa144kx2i |
| PubChem CID | 10824 |
| IUPAC Name | 3-methoxyaniline |
| SMILES | COC1=CC=CC(=C1)N |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAA1081518
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Thermo Scientific Chemicals
A1081518 |
50 g |
Each for $76.05
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AAA1081530
|
Thermo Scientific Chemicals
A1081530 |
250 g |
Each for $239.81
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AAA108150B
|
Thermo Scientific Chemicals
A108150B |
1000 g |
Each for $685.44
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Description
The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsThe unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.
Solubility
Soluble in water(18g/L).
Notes
Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
Chemical Identifiers
| 536-90-3 | |
| 123.155 | |
| NCBZRJODKRCREW-UHFFFAOYSA-N | |
| 10824 | |
| COC1=CC=CC(=C1)N |
| C7H9NO | |
| MFCD00007783 | |
| m-anisidine, 3-aminoanisole, m-methoxyaniline, 3-methoxybenzenamine, 3-anisidine, m-aminoanisole, benzenamine, 3-methoxy, m-anisylamine, 1-amino-3-methoxybenzene, unii-jxa144kx2i | |
| 3-methoxyaniline |
Specifications
| 536-90-3 | |
| 1.101 | |
| 126°C (258°F) | |
| C7H9NO | |
| MFCD00007783 | |
| UN2431 | |
| Light sensitive | |
| m-anisidine, 3-aminoanisole, m-methoxyaniline, 3-methoxybenzenamine, 3-anisidine, m-aminoanisole, benzenamine, 3-methoxy, m-anisylamine, 1-amino-3-methoxybenzene, unii-jxa144kx2i | |
| NCBZRJODKRCREW-UHFFFAOYSA-N | |
| 3-methoxyaniline | |
| 10824 | |
| 98% |
| -1°C | |
| 250°C to 251°C | |
| Characteristic | |
| 1.581 | |
| 50 g | |
| 386119 | |
| 14,667 | |
| Soluble in water(18g/L). | |
| COC1=CC=CC(=C1)N | |
| 123.155 | |
| 123.16 | |
| m-Anisidine |
Safety and Handling
GHS H Statement
H311-H373-H302-H332
Toxic in contact with skin.
May cause damage to organs through prolonged or repeated exposure.
Harmful if swallowed.
Harmful if inhaled.
P260-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P314-P330-P361-P363-P501c
H302+H332-H311-H373
DOTInformation : Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: ANISIDINES
EINECSNumber : 208-651-4
RTECSNumber : BZ5408000
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only