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Lithium aluminum hydride, 95% min
Reducing Agent For Pharmaceuticals, Perfumes, and Fine organic Chemicals; Source of Hydrogen | CAS: 16853-85-3 | AlH4Li | 37.95 g/mol
Supplier: Thermo Scientific Chemicals 01344222
Description
Reducing agent for pharmaceuticals, perfumes and fine organic chemicals; source of hydrogen, propellant, and catalyst in polymerizationsLithium aluminum hydride is used as a reducing agent in various synthetic organic chemistry reactions. For example, it is used in the conversion of esters, carboxylic acids, acyl chlorides, aldehydes and ketones into their corresponding alcohols. It is also involved in the conversion of amide, nitro, nitrile, imine, oxime and azide compounds into their amines as well as reduces alkyl halides to alkanes. It reacts with sodium chloride to prepare sodium hydride. It acts as a potential hydrogen storage medium, which could be used for future fuel cell-powered vehicles. It is mainly used in the preparation of other tetrahydridoaluminumates like sodium aluminum hydride, potassium aluminum hydride and magnesium alanate. Furthermore, it has been used to prepare thermoplastic polyester polyamides from oleic acid and lithium-polymer batteries.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Specifications
Lithium aluminum hydride | |
16853-85-3 | |
Powder | |
AlH4Li | |
UN1410 | |
lithium aluminum hydride, lithium aluminum hydride, aluminum lithium hydride, lithiumaluminiumhydride, aluminum iii lithium hydride, lithium alanate, lithium aluminum tetrahydride, lithiumaluminiumhydrid, litiumaluminum hydride, lithim aluminum hydride | |
OCZDCIYGECBNKL-UHFFFAOYSA-N | |
lithium(1+) alumanuide | |
21226445 | |
≥95% | |
Air and moisture sensitive |
>125°C (decomposition) | |
White to Gray | |
100 g | |
MFCD00011075 | |
14,349 | |
Decomposes in water; Soluble in ether,diethyl ether and terahydrofuran. | |
[Li+].[AlH4-] | |
37.95 | |
37.95 | |
Odorless | |
0.917 |
Chemical Identifiers
16853-85-3 | |
37.95 | |
OCZDCIYGECBNKL-UHFFFAOYSA-N | |
21226445 | |
[Li+].[AlH4-] |
AlH4Li | |
MFCD00011075 | |
lithium aluminum hydride, lithium aluminum hydride, aluminum lithium hydride, lithiumaluminiumhydride, aluminum iii lithium hydride, lithium alanate, lithium aluminum tetrahydride, lithiumaluminiumhydrid, litiumaluminum hydride, lithim aluminum hydride | |
lithium(1+) alumanuide |
Safety and Handling
GHS H Statement
H260-H301-H314-H318;
In contact with water releases flammable gases which may ignite spontaneously.
Toxic if swallowed.
Causes severe skin burns and eye damage.
Causes serious eye damage.
P223-P231+P232-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P335+P334-P363-P370+P378q-P501c
H260-H314-H500
DOTInformation : Transport Hazard Class: 4.3; Packing Group: I; Proper Shipping Name: LITHIUM ALUMINUM HYDRIDE
EINECSNumber : 240-877-9
RTECSNumber : BD0100000
TSCA : Yes
Recommended Storage : Ambient temperatures; Store under Argon
RUO – Research Use Only