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Diphenyliodonium hexafluorophosphate, 98%

CAS: 58109-40-3 | C12H10I | 281.12 g/mol

$211.18 - $2387.40

Chemical Identifiers

CAS 58109-40-3
Molecular Formula C12H10I
Molecular Weight (g/mol) 281.12
MDL Number MFCD00061398
InChI Key OZLBDYMWFAHSOQ-UHFFFAOYSA-N
Synonym diphenyliodonium hexafluorophosphate, diphenyliodanium hexafluorophosphate, diphenyliodonium hexafluorophosphate v, iodonium, diphenyl-, hexafluorophosphate 1-, iodonium, diphenyl-, hexafluorophosphate 1-1:1, diphenyliodonium pf6, dpihfp, acmc-209m2o, phi + pf6-, diphenyliodanium; hexafluoro-$l^ 5-phosphanuide
PubChem CID 2737136
IUPAC Name diphenyliodanium
SMILES [I+](C1=CC=CC=C1)C1=CC=CC=C1
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AAA1793409
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Thermo Scientific Chemicals
A1793409
10 g
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AAA1793418
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Thermo Scientific Chemicals
A1793418
50 g
Each for $730.18
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AAA1793430
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Thermo Scientific Chemicals
A1793430
250 g
Each for $2,387.40
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Description

Description

Diphenyliodonium hexafluorophosphate is used as cationic photoinitiator and photoacid generator. It acts as a catalyst for the photochemical polymerization of various monomers. Further, it used as arylating reagent as well as an oxidant in organic synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diphenyliodonium hexafluorophosphate is used as cationic photoinitiator and photoacid generator. It acts as a catalyst for the photochemical polymerization of various monomers. Further, it used as arylating reagent as well as an oxidant in organic synthesis.

Solubility
Soluble in tetrahydrofuran, ethyl acetate, methanol, acetonitrile, dimethylformamide, dimethyl carbonate. Sparingly soluble in chloroform and dichloromethane. Insoluble in pentanes, hexanes, toluene and diethyl ether.

Notes
Light sensitive and hygroscopic. Incompatible with strong acids.
Specifications

Chemical Identifiers

58109-40-3
281.12
OZLBDYMWFAHSOQ-UHFFFAOYSA-N
2737136
[I+](C1=CC=CC=C1)C1=CC=CC=C1
C12H10I
MFCD00061398
diphenyliodonium hexafluorophosphate, diphenyliodanium hexafluorophosphate, diphenyliodonium hexafluorophosphate v, iodonium, diphenyl-, hexafluorophosphate 1-, iodonium, diphenyl-, hexafluorophosphate 1-1:1, diphenyliodonium pf6, dpihfp, acmc-209m2o, phi + pf6-, diphenyliodanium; hexafluoro-$l^ 5-phosphanuide
diphenyliodanium

Specifications

58109-40-3
C12H10I
10 g
Light sensitive
Soluble in tetrahydrofuran,ethyl acetate,methanol,acetonitrile,dimethylformamide,dimethyl carbonate. Sparingly soluble in chloroform and dichloromethane. Insoluble in pentanes,hexanes,toluene and diethyl ether.
[I+](C1=CC=CC=C1)C1=CC=CC=C1
281.12
426.08
Diphenyliodonium hexafluorophosphate
139°C to 144°C
MFCD00061398
UN2811
diphenyliodonium hexafluorophosphate, diphenyliodanium hexafluorophosphate, diphenyliodonium hexafluorophosphate v, iodonium, diphenyl-, hexafluorophosphate 1-, iodonium, diphenyl-, hexafluorophosphate 1-1:1, diphenyliodonium pf6, dpihfp, acmc-209m2o, phi + pf6-, diphenyliodanium; hexafluoro-$l^ 5-phosphanuide
OZLBDYMWFAHSOQ-UHFFFAOYSA-N
diphenyliodanium
2737136
98%
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Safety and Handling

Safety and Handling

GHS H Statement
H331-H302-H312-H315-H319-H335
Toxic if inhaled.
Harmful if swallowed.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

H314-H335

DOTInformation : Hazard Class: 8; Packaging Group: II

EINECSNumber : 261-134-5

TSCA : Yes

Recommended Storage : Ambient temperatures

SDS
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RUO – Research Use Only