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Diphenyl sulfoxide, 98+%

CAS: 945-51-7 | C12H10OS | 202.271 g/mol

Supplier:  Thermo Scientific Chemicals B2213514

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Catalog No. AAB2213514


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Description

Description

Diphenyl sulfoxide is a reagent used as an oxidant and hydroxyl activator in combination with a variety of electrophilic reagents. Efficient glycosidation of a phenyl thiosialoside donor with diphenyl sulfoxide and triflic anhydride in dichloromethane was reported. Direct glycosylations with 1-hydroxy glycosyl donors is made using trifluoromethanesulfonic anhydride and diphenyl sulfoxide. The preparation of triarylsulfonium halides was by the action of aryl Grignard reagents on diphenyl sulfoxide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diphenyl sulfoxide is a reagent used as an oxidant and hydroxyl activator in combination with a variety of electrophilic reagents. Efficient glycosidation of a phenyl thiosialoside donor with diphenyl sulfoxide and triflic anhydride in dichloromethane was reported. Direct glycosylations with 1-hydroxy glycosyl donors is made using trifluoromethanesulfonic anhydride and diphenyl sulfoxide. The preparation of triarylsulfonium halides was by the action of aryl Grignard reagents on diphenyl sulfoxide.

Solubility
Soluble in water. Soluble in most organic solvents.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
Specifications

Specifications

Diphenyl sulfoxide
69°C to 72°C
C12H10OS
25 g
diphenyl sulfoxide, phenyl sulfoxide, sulfinyldibenzene, phenylsulfinylbenzene, diphenyl sulphoxide, sulfoxide, diphenyl, diphenylsulfoxide, benzene, 1,1'-sulfinylbis, 1,1'-sulfinyldibenzene, phenylsulfinyl benzene
JJHHIJFTHRNPIK-UHFFFAOYSA-N
benzenesulfinylbenzene
13679
≥98%
945-51-7
206°C to 208°C (13 mmHg)
MFCD00002085
1908444
Soluble in water. Soluble in most organic solvents.
C1=CC=C(C=C1)S(=O)C2=CC=CC=C2
202.271
202.28

Chemical Identifiers

945-51-7
202.271
JJHHIJFTHRNPIK-UHFFFAOYSA-N
13679
C1=CC=C(C=C1)S(=O)C2=CC=CC=C2
C12H10OS
MFCD00002085
diphenyl sulfoxide, phenyl sulfoxide, sulfinyldibenzene, phenylsulfinylbenzene, diphenyl sulphoxide, sulfoxide, diphenyl, diphenylsulfoxide, benzene, 1,1'-sulfinylbis, 1,1'-sulfinyldibenzene, phenylsulfinyl benzene
benzenesulfinylbenzene
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Safety and Handling

Safety and Handling

EINECSNumber : 213-415-9

RTECSNumber : DA9185000

TSCA : Yes

Recommended Storage : Ambient temperatures

SDS
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