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(+)-Diethyl L-tartrate, 98%
CAS: 87-91-2 | C8H14O6 | 206.19 g/mol
Supplier: Thermo Scientific Chemicals A1064136
Description
(+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications(+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.
Solubility
Fully miscible in water.
Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.
Specifications
(+)-Diethyl L-tartrate | |
17°C | |
280°C | |
C8H14O6 | |
MFCD00009143 | |
1727145 | |
diethyl l-+-tartrate, 2r,3r-diethyl 2,3-dihydroxysuccinate, l +-diethyl l-tartrate, +-diethyl l-tartrate, diethyl l-tartrate, diethyl-l-tartrate, unii-oq72cpy58z, l-+-tartaric acid diethyl ester, diethyl l-tartarate, tartaric acid, diethyl ester, r,r | |
YSAVZVORKRDODB-UHFFFAOYNA-N | |
CCOC(=O)C(O)C(O)C(=O)OCC | |
206.19 | |
206.19 |
87-91-2 | |
1.205 | |
93°C (199°F) | |
1.446 | |
500 g | |
14,3855 | |
Fully miscible in water. | |
+27° (c=1 in water) | |
diethyl (2R,3R)-2,3-dihydroxybutanedioate | |
6993580 | |
98% |
Chemical Identifiers
87-91-2 | |
206.19 | |
YSAVZVORKRDODB-UHFFFAOYNA-N | |
6993580 |
C8H14O6 | |
MFCD00009143 | |
diethyl l-+-tartrate, 2r,3r-diethyl 2,3-dihydroxysuccinate, l +-diethyl l-tartrate, +-diethyl l-tartrate, diethyl l-tartrate, diethyl-l-tartrate, unii-oq72cpy58z, l-+-tartaric acid diethyl ester, diethyl l-tartarate, tartaric acid, diethyl ester, r,r | |
CCOC(=O)C(O)C(O)C(=O)OCC |
Safety and Handling
GHS H Statement
H227
Combustible liquid.
P210-P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362-P370+P378q-P501c
H227-H315-H319
EINECSNumber : 201-783-3
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only