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Dichlorotris(triphenylphosphine)ruthenium(II), Premion™, 99.95% (metals basis), Ru 10.2% min
CAS: 15529-49-4 | C54H45Cl2P3Ru | 958.85 g/mol
$125.27 - $483.21
Chemical Identifiers
CAS | 15529-49-4 |
---|---|
Molecular Formula | C54H45Cl2P3Ru |
Molecular Weight (g/mol) | 958.85 |
MDL Number | MFCD00013077 |
InChI Key | KSHWMFNJCNGTJO-UHFFFAOYSA-L |
Synonym | dichlorotris triphenylphosphine ruthenium ii, tris triphenylphosphine ruthenium ii chloride, dichlorotris triphenylphosphino ruthenium ii, tris triphenylphosphine ruthenium ii dichloride, dichlorotris triphenylphosphine ruthenium, ruthenium ii-tris triphenylphosphine dichloride, tris triphenylphosphine dichlororuthenium, ruthenium dichlorotris triphenylphosphine, pubchem12822 |
PubChem CID | 11007548 |
IUPAC Name | dichlororuthenium;triphenylphosphane |
SMILES | [Cl-].[Cl-].[Ru+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1 |
Description
Dichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Chemical Identifiers
15529-49-4 | |
958.85 | |
KSHWMFNJCNGTJO-UHFFFAOYSA-L | |
11007548 | |
[Cl-].[Cl-].[Ru+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1 |
C54H45Cl2P3Ru | |
MFCD00013077 | |
dichlorotris triphenylphosphine ruthenium ii, tris triphenylphosphine ruthenium ii chloride, dichlorotris triphenylphosphino ruthenium ii, tris triphenylphosphine ruthenium ii dichloride, dichlorotris triphenylphosphine ruthenium, ruthenium ii-tris triphenylphosphine dichloride, tris triphenylphosphine dichlororuthenium, ruthenium dichlorotris triphenylphosphine, pubchem12822 | |
dichlororuthenium;triphenylphosphane |
Specifications
15529-49-4 | |
Brown to Black | |
MFCD00013077 | |
Air and moisture sensitive | |
Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene | |
[Cl-].[Cl-].[Ru+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1 | |
958.85 | |
958.86 | |
Premion™ | |
Crystalline Powder | |
(metals basis) |
132°C to 134°C | |
C54H45Cl2P3Ru | |
1 g | |
dichlorotris triphenylphosphine ruthenium ii, tris triphenylphosphine ruthenium ii chloride, dichlorotris triphenylphosphino ruthenium ii, tris triphenylphosphine ruthenium ii dichloride, dichlorotris triphenylphosphine ruthenium, ruthenium ii-tris triphenylphosphine dichloride, tris triphenylphosphine dichlororuthenium, ruthenium dichlorotris triphenylphosphine, pubchem12822 | |
KSHWMFNJCNGTJO-UHFFFAOYSA-L | |
dichlororuthenium;triphenylphosphane | |
11007548 | |
99.95% | |
Ru 10.2% min. | |
Dichlorotris(triphenylphosphine)ruthenium(II) |
Safety and Handling
P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P330-P363-P501c
H302+H312+H332
DOTInformation : Hazard Class: 6.1; Packaging Group: III
EINECSNumber : 239-569-7
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only