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Dibenzyl carbonate, 98%
CAS: 3459-92-5 | C15H14O3 | 242.27 g/mol
Supplier: Thermo Scientific Chemicals A1146418
Description
Ionic liquids can effectively accelerate slow N-benzylation reactions utilizing dibenzyl carbonate as an alkylating reagent. Dibenzyl carbonate (DBzlC) has been used to benzylate phenylacetonitrile, benzyl phenylacetate and phenol. Selective N, N-dibenzylation of primary aliphatic amines was carried with dibenzyl carbonate in the presence of phosphonium salts.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsIonic liquids can effectively accelerate slow N-benzylation reactions utilizing dibenzyl carbonate as an alkylating reagent. Dibenzyl carbonate (DBzlC) has been used to benzylate phenylacetonitrile, benzyl phenylacetate and phenol. Selective N, N-dibenzylation of primary aliphatic amines was carried with dibenzyl carbonate in the presence of phosphonium salts.
Solubility
Sparingly Soluble (0.099 g/L) (25°C).
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, heat.
Specifications
| Dibenzyl carbonate | |
| 27°C to 30°C | |
| >110°C (230°F) | |
| 1.5485 | |
| 50 g | |
| Air sensitive | |
| Sparingly Soluble (0.099g/L) (25°C). | |
| O=C(OCC1=CC=CC=C1)OCC1=CC=CC=C1 | |
| 242.27 | |
| 242.27 |
| 3459-92-5 | |
| 150°C to 155°C (0.8 mmHg) | |
| C15H14O3 | |
| MFCD00014436 | |
| 1882864 | |
| carbonic acid, bis phenylmethyl ester, benzyl carbonate, carbonic acid, dibenzyl ester, dibenzylcarbonate, carbonic acid dibenzyl ester, phenylmethyl phenylmethoxy formate, dibenzyl carbonate, acmc-209i8r, carbonic acid,bis phenylmethyl ester | |
| PIZLBWGMERQCOC-UHFFFAOYSA-N | |
| dibenzyl carbonate | |
| 77002 | |
| 98% |
Chemical Identifiers
| 3459-92-5 | |
| 242.27 | |
| PIZLBWGMERQCOC-UHFFFAOYSA-N | |
| 77002 | |
| O=C(OCC1=CC=CC=C1)OCC1=CC=CC=C1 |
| C15H14O3 | |
| MFCD00014436 | |
| carbonic acid, bis phenylmethyl ester, benzyl carbonate, carbonic acid, dibenzyl ester, dibenzylcarbonate, carbonic acid dibenzyl ester, phenylmethyl phenylmethoxy formate, dibenzyl carbonate, acmc-209i8r, carbonic acid,bis phenylmethyl ester | |
| dibenzyl carbonate |
Safety and Handling
P264b-P270-P280-P301+P312-P302+P352-P312-P330-P363-P501c
H302+H312
EINECSNumber : 222-401-1
TSCA : Yes
Recommended Storage : Keep cold; Store under Argon
RUO – Research Use Only