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Chlorotris(triphenylphosphine)rhodium(I), 97%
CAS: 14694-95-2 | C54H45ClP3Rh | 925.23 g/mol
$540.18 - $540.18
Chemical Identifiers
| CAS | 14694-95-2 |
|---|---|
| Molecular Formula | C54H45ClP3Rh |
| Molecular Weight (g/mol) | 925.23 |
| MDL Number | MFCD00010016 |
| InChI Key | IXAYKDDZKIZSPV-UHFFFAOYSA-M |
| Synonym | chlorotris triphenylphosphine rhodium i, chlorotris triphenylphosphine rhodium, tris triphenylphosphine rhodium i chloride, tris triphenylphosphine chlororhodium, wilkinson's catalyst, unii-0fv534bkev, tris triphenylphosphine rhodium chloride, 0fv534bkev, rhodium; triphenylphosphane; chloride |
| PubChem CID | 84599 |
| IUPAC Name | rhodium;triphenylphosphane;chloride |
| SMILES | [Cl-].[Rh+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1 |
Description
Chlorotris(triphenylphosphine)rhodium(I) is used as a homogeneous hydrogenation catalyst. It is used in the selective hydrogenation of alkenes and alkynes.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Chemical Identifiers
| 14694-95-2 | |
| 925.23 | |
| IXAYKDDZKIZSPV-UHFFFAOYSA-M | |
| 84599 | |
| [Cl-].[Rh+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1 |
| C54H45ClP3Rh | |
| MFCD00010016 | |
| chlorotris triphenylphosphine rhodium i, chlorotris triphenylphosphine rhodium, tris triphenylphosphine rhodium i chloride, tris triphenylphosphine chlororhodium, wilkinson's catalyst, unii-0fv534bkev, tris triphenylphosphine rhodium chloride, 0fv534bkev, rhodium; triphenylphosphane; chloride | |
| rhodium;triphenylphosphane;chloride |
Specifications
| 14694-95-2 | |
| Red | |
| C54H45ClP3Rh | |
| MFCD00010016 | |
| 14,10047 | |
| Soluble in most solvents (e;g; benzene,ethanol,chloroform,dichloromethane) but with phosphine dissociation; Reacts with O2 in solution | |
| [Cl-].[Rh+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1 | |
| 925.23 | |
| 925.23 | |
| Micro Crystals |
| ∼250°C (decomposition) | |
| Odorless | |
| RhCl[(C6H5)3P]3 | |
| 1 g | |
| chlorotris triphenylphosphine rhodium i, chlorotris triphenylphosphine rhodium, tris triphenylphosphine rhodium i chloride, tris triphenylphosphine chlororhodium, wilkinson's catalyst, unii-0fv534bkev, tris triphenylphosphine rhodium chloride, 0fv534bkev, rhodium; triphenylphosphane; chloride | |
| IXAYKDDZKIZSPV-UHFFFAOYSA-M | |
| rhodium;triphenylphosphane;chloride | |
| 84599 | |
| 97% | |
| Chlorotris(triphenylphosphine)rhodium(I) |
Safety and Handling
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
H315-H319-H335
EINECSNumber : 238-744-5
TSCA : Yes
storageNote1 : 2°C to 8°C
Recommended Storage : Keep cold
RUO – Research Use Only