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Chloro(1,5-cyclooctadiene)rhodium(I) dimer
CAS: 12092-47-6 | C16H24Cl2Rh2 | 493.08 g/mol
$381.19 - $946.73
Chemical Identifiers
| CAS | 12092-47-6 |
|---|---|
| Molecular Formula | C16H24Cl2Rh2 |
| Molecular Weight (g/mol) | 493.08 |
| MDL Number | MFCD00012415 |
| InChI Key | QSUDXYGZLAJAQU-MIXQCLKLSA-L |
| Synonym | chloro 1,5-cyclooctadiene rhodium i dimer, 1z,5z-cycloocta-1,5-diene; rhodium; dichloride, bis 1,5-cyclooctadiene dirhodium i dichloride, 1,5-cyclooctadiene rhodium chloride dimer, ccris 5036, di-?-chlorobis 1,2,5,6-?-1,5-cyclooctadiene diiridium, rhodium-1,5-cyclooctadiene chloride, 1,5-cyclooctadiene-iridium i chloride dimer, chloro 1,5-cyclooctadiene iridium i dimer |
| PubChem CID | 6436379 |
| IUPAC Name | (1Z,5Z)-cycloocta-1,5-diene;rhodium;dichloride |
| SMILES | [Cl-].[Cl-].[Rh+].[Rh+].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1 |
Description
It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Chemical Identifiers
| 12092-47-6 | |
| 493.08 | |
| QSUDXYGZLAJAQU-MIXQCLKLSA-L | |
| 6436379 | |
| [Cl-].[Cl-].[Rh+].[Rh+].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1 |
| C16H24Cl2Rh2 | |
| MFCD00012415 | |
| chloro 1,5-cyclooctadiene rhodium i dimer, 1z,5z-cycloocta-1,5-diene; rhodium; dichloride, bis 1,5-cyclooctadiene dirhodium i dichloride, 1,5-cyclooctadiene rhodium chloride dimer, ccris 5036, di-?-chlorobis 1,2,5,6-?-1,5-cyclooctadiene diiridium, rhodium-1,5-cyclooctadiene chloride, 1,5-cyclooctadiene-iridium i chloride dimer, chloro 1,5-cyclooctadiene iridium i dimer | |
| (1Z,5Z)-cycloocta-1,5-diene;rhodium;dichloride |
Specifications
| 12092-47-6 | |
| Yellow to Orange | |
| C16H24Cl2Rh2 | |
| 250 mg | |
| chloro 1,5-cyclooctadiene rhodium i dimer, 1z,5z-cycloocta-1,5-diene; rhodium; dichloride, bis 1,5-cyclooctadiene dirhodium i dichloride, 1,5-cyclooctadiene rhodium chloride dimer, ccris 5036, di-?-chlorobis 1,2,5,6-?-1,5-cyclooctadiene diiridium, rhodium-1,5-cyclooctadiene chloride, 1,5-cyclooctadiene-iridium i chloride dimer, chloro 1,5-cyclooctadiene iridium i dimer | |
| QSUDXYGZLAJAQU-MIXQCLKLSA-L | |
| (1Z,5Z)-cycloocta-1,5-diene;rhodium;dichloride | |
| 6436379 | |
| Crystalline |
| 243°C (decomposition) | |
| Odorless | |
| MFCD00012415 | |
| Air sensitive; Hygroscopic | |
| Soluble in chloroform,dichloromethane,and methanol; Sparingly soluble in most common solvents. | |
| [Cl-].[Cl-].[Rh+].[Rh+].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1 | |
| 493.08 | |
| 493.08 | |
| Chloro(1,5-cyclooctadiene)rhodium(I) dimer |
Safety and Handling
EINECSNumber : 235-157-6
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only