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Benzyl 2,2,2-trichloroacetimidate, 98%
CAS: 81927-55-1 | C9H8Cl3NO | 252.52 g/mol
Supplier: Thermo Scientific Chemicals A1238714
Description
Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups. It acts as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It can also be used for mild esterification of carboxylic acids in the presence of a catalytic amount of BF3 etherate.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsBenzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups. It acts as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It can also be used for mild esterification of carboxylic acids in the presence of a catalytic amount of BF3 etherate.
Solubility
Miscible with cyclohexane/dichloromethane.
Notes
Moisture and light sensitive. Incompatible with strong oxidizing agents and strong acids.
Specifications
| Benzyl 2,2,2-trichloroacetimidate | |
| 1.356 | |
| >110°C (230°F) | |
| 1.545 | |
| 25 g | |
| Moisture sensitive | |
| Miscible with cyclohexane/dichloromethane. | |
| ClC(Cl)(Cl)C(=N)OCC1=CC=CC=C1 | |
| 252.52 | |
| 252.53 |
| 81927-55-1 | |
| 110°C to 114°C (0.5 mmHg) | |
| C9H8Cl3NO | |
| MFCD00000805 | |
| 2525375 | |
| benzyl 2,2,2-trichloroacetimidate, benzyl trichloroacetimidate, benzyltrichloroacetimidate, trichloroacetimidic acid benzyl ester, 2,2,2-trichloro-1-phenylmethoxy ethanimine, ethanimidic acid, 2,2,2-trichloro-, phenylmethyl ester, benzyl 2,2,2-trichloroethanecarboximidate, benzyl2,2,2-trichloroacetimidate, acmc-209pmn, benzyl trichloracetimidate | |
| HUZCTWYDQIQZPM-UHFFFAOYSA-N | |
| benzyl 2,2,2-trichloroethanimidate | |
| 144968 | |
| 98% |
Chemical Identifiers
| 81927-55-1 | |
| 252.52 | |
| HUZCTWYDQIQZPM-UHFFFAOYSA-N | |
| benzyl 2,2,2-trichloroethanimidate |
| C9H8Cl3NO | |
| MFCD00000805 | |
| 144968 | |
| ClC(Cl)(Cl)C(=N)OCC1=CC=CC=C1 |
Safety and Handling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
H315-H319-H335
EINECSNumber : 617-271-1
TSCA : No
Recommended Storage : Keep cold; Store under Nitrogen
RUO – Research Use Only