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Aluminum chloride, anhydrous, granular, 99%
CAS: 7446-70-0 | AlCl3 | 133.33 g/mol
Supplier: Thermo Scientific Chemicals A1189230
Description
Aluminum chloride is used as a catalyst for Friedel-Crafts acylation and alkylation of aromatic compounds. It is one of the most commonly employed Lewis acids for a wide variety of organic transformations. It catalyzes the ene reaction, polymerization and isomerization reactions. For example, it can be used for the synthesis of ethyl benzene which is a precursor for producing polystyrene. It can be used for producing dodecylbenzene, a key intermediate for detergents. It is useful in the production of anthroquinone, the presursor for dyestuffs. It is used in the synthesis of bis (arene) metal complexes, through Fischer-Hafner synthesis. Gattermann-Koch reaction employs aluminum chloride for introducing formyl group onto aromatic rings.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsAluminum chloride is used as a catalyst for Friedel-Crafts acylation and alkylation of aromatic compounds. It is one of the most commonly employed Lewis acids for a wide variety of organic transformations. It catalyzes the ene reaction, polymerization and isomerization reactions. For example, it can be used for the synthesis of ethyl benzene which is a precursor for producing polystyrene. It can be used for producing dodecylbenzene, a key intermediate for detergents. It is useful in the production of anthroquinone, the presursor for dyestuffs. It is used in the synthesis of bis (arene) metal complexes, through Fischer-Hafner synthesis. Gattermann-Koch reaction employs aluminum chloride for introducing formyl group onto aromatic rings.
Solubility
Soluble in water, hydrochloric acid and ethanol. Slightly soluble in benzene.
Notes
Moisture sensitive. Reacts violently with water with liberation of heat.
Specifications
Aluminum chloride | |
Anhydrous | |
2.4 | |
250 g | |
MFCD00003422 | |
14,337 | |
Soluble in water,hydrochloric acid and ethanol. Slightly soluble in benzene. | |
[Al+3].[Cl-].[Cl-].[Cl-] | |
133.33 | |
99% | |
Moisture sensitive |
190°C (sublimation) | |
7446-70-0 | |
Granules | |
AlCl3 | |
UN1726 | |
aluminum chloride anhydrous, aluminum iii chloride, aluminiumchloride, aluminumchloride, aluminum chlorid, aluminum cloride, alumimum chloride, aluminum-chloride, trichloroaluminium, chloride aluminum | |
VSCWAEJMTAWNJL-UHFFFAOYSA-K | |
aluminum(3+) trichloride | |
133.34 | |
Pungent | |
2.44 |
Chemical Identifiers
7446-70-0 | |
133.33 | |
VSCWAEJMTAWNJL-UHFFFAOYSA-K | |
aluminum(3+) trichloride |
AlCl3 | |
MFCD00003422 | |
aluminum chloride anhydrous, aluminum iii chloride, aluminiumchloride, aluminumchloride, aluminum chlorid, aluminum cloride, alumimum chloride, aluminum-chloride, trichloroaluminium, chloride aluminum | |
[Al+3].[Cl-].[Cl-].[Cl-] |
Safety and Handling
GHS H Statement
H314
Causes severe skin burns and eye damage.
P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
H314-H335
DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: ALUMINUM CHLORIDE, ANHYDROUS
EINECSNumber : 231-208-1
RTECSNumber : BD0525000
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only