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Allyltri-n-butyltin, 97%
CAS: 24850-33-7 | C15H32Sn | 331.13 g/mol
Supplier: Thermo Scientific Chemicals L1408706
Description
Allyltri-n-butyltin acts as an allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate. It is also used to prepare homoallylic alcohols with trichloro-1,3,5-triazene. Further, it plays an important role for tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reaction with iodoquinones and allyl acetates.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsAllyltri-n-butyltin acts as an allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate. It is also used to prepare homoallylic alcohols with trichloro-1,3,5-triazene. Further, it plays an important role for tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reaction with iodoquinones and allyl acetates.
Solubility
Immiscible with water.
Notes
Air sensitive. Incompatible with strong oxidizing agents.
Specifications
| Allyltri-n-butyltin | |
| 1.079 | |
| 103°C (217°F) | |
| 1.486 | |
| 5 g | |
| 3588340 | |
| allyltributyltin, allyltributylstannane, allyltri-n-butyltin, stannane, tributyl-2-propenyl, tributyl prop-2-en-1-yl stannane, allyl tributyl stannane, unii-aor8od4103, tributyl-2-propenylstannane, tri-n-butyl-2-propenylstannane, allyl tributyltin | |
| YLGRTLMDMVAFNI-UHFFFAOYSA-N | |
| tributyl(prop-2-enyl)stannane | |
| 90628 | |
| 97% |
| 24850-33-7 | |
| 100°C to 102°C (0.5 mmHg) | |
| C15H32Sn | |
| MFCD00010346 | |
| UN2788 | |
| Air sensitive | |
| Immiscible with water. | |
| CCCC[Sn](CCCC)(CCCC)CC=C | |
| 331.13 | |
| 331.12 |
Chemical Identifiers
| 24850-33-7 | |
| 331.13 | |
| YLGRTLMDMVAFNI-UHFFFAOYSA-N | |
| 90628 |
| C15H32Sn | |
| MFCD00010346 | |
| allyltributyltin, allyltributylstannane, allyltri-n-butyltin, stannane, tributyl-2-propenyl, tributyl prop-2-en-1-yl stannane, allyl tributyl stannane, unii-aor8od4103, tributyl-2-propenylstannane, tri-n-butyl-2-propenylstannane, allyl tributyltin | |
| CCCC[Sn](CCCC)(CCCC)CC=C |
Safety and Handling
GHS H Statement
H301-H372-H312-H315-H319
Toxic if swallowed.
Causes damage to organs through prolonged or repeated exposure.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
P260-P264b-P270-P280-P301+P310-P302+P352-P305+P351+P338-P312-P314-P330-P332+P313-P362-P501c
H301-H312-H315-H319-H372
DOTInformation : Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: ORGANOTIN COMPOUNDS, LIQUID, N.O.S.
EINECSNumber : 246-494-3
TSCA : No
Recommended Storage : Keep cold; Store under Argon
RUO – Research Use Only