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2-Chloro-4H-1,3,2-benzodioxaphosphorin-4-one, 97%
CAS: 5381-99-7 | C7H4ClO3P | 202.53 g/mol
$156.40 - $485.47
Chemical Identifiers
| CAS | 5381-99-7 |
|---|---|
| Molecular Formula | C7H4ClO3P |
| Molecular Weight (g/mol) | 202.53 |
| MDL Number | MFCD00013353 |
| InChI Key | BVOITXUNGDUXRW-UHFFFAOYNA-N |
| Synonym | 2-chloro-4h-1,3,2-benzodioxaphosphorin-4-one, 2-chloro-4h-benzo d 1,3,2 dioxaphosphinin-4-one, van boom's reagent, 2-chloro-4h-1,2,3-benzodioxaphosphorin-4-one, 4h-1,3,2-benzodioxaphosphorin-4-one, 2-chloro, salicylchlorophosphite, salicyl chlorophosphite, acmc-1an3b, 2-chloro-4h-1,3,2-benzodioxaphosphinin-4-one, salicylchlorophosphite; van boom's reagent |
| PubChem CID | 237010 |
| IUPAC Name | 2-chloro-1,3,2-benzodioxaphosphinin-4-one |
| SMILES | ClP1OC(=O)C2=CC=CC=C2O1 |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAB2108606
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Thermo Scientific Chemicals
B2108606 |
5 g |
Each for $156.40
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AAB2108614
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Thermo Scientific Chemicals
B2108614 |
25 g |
Each for $485.47
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Description
2-Chloro-4H-1,3,2-benzodioxaphosphorin-4-one is a reagent used in phosphorylation and phosphitylation of alcohols and in the formation of H-phosphonates. It is also reactive cyclic phosphitylating reagent involved in fast coupling rates and hydrolytic cleavage more readily compare to that of a acyclic analog.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications2-Chloro-4H-1,3,2-benzodioxaphosphorin-4-one is a reagent used in phosphorylation and phosphitylation of alcohols and in the formation of H-phosphonates. It is also reactive cyclic phosphitylating reagent involved in fast coupling rates and hydrolytic cleavage more readily compare to that of a acyclic analog.
Solubility
Soluble in acetonitrile, dichloromethane, tetrahydrofuron and dimethylformamide.
Notes
Light and heat sensitive. Incompatible with water and strong oxidizing agents.
Chemical Identifiers
| 5381-99-7 | |
| 202.53 | |
| BVOITXUNGDUXRW-UHFFFAOYNA-N | |
| 237010 | |
| ClP1OC(=O)C2=CC=CC=C2O1 |
| C7H4ClO3P | |
| MFCD00013353 | |
| 2-chloro-4h-1,3,2-benzodioxaphosphorin-4-one, 2-chloro-4h-benzo d 1,3,2 dioxaphosphinin-4-one, van boom's reagent, 2-chloro-4h-1,2,3-benzodioxaphosphorin-4-one, 4h-1,3,2-benzodioxaphosphorin-4-one, 2-chloro, salicylchlorophosphite, salicyl chlorophosphite, acmc-1an3b, 2-chloro-4h-1,3,2-benzodioxaphosphinin-4-one, salicylchlorophosphite; van boom's reagent | |
| 2-chloro-1,3,2-benzodioxaphosphinin-4-one |
Specifications
| 5381-99-7 | |
| 127°C to 128°C (11 mmHg) | |
| C7H4ClO3P | |
| 5 g | |
| Moisture sensitive | |
| Soluble in acetonitrile,dichloromethane,tetrahydrofuron and dimethylformamide. | |
| ClP1OC(=O)C2=CC=CC=C2O1 | |
| 202.53 | |
| 202.54 | |
| 2-Chloro-4H-1,3,2-benzodioxaphosphorin-4-one |
| 36°C to 40°C | |
| >110°C (230°F) | |
| MFCD00013353 | |
| UN3261 | |
| 2-chloro-4h-1,3,2-benzodioxaphosphorin-4-one, 2-chloro-4h-benzo d 1,3,2 dioxaphosphinin-4-one, van boom's reagent, 2-chloro-4h-1,2,3-benzodioxaphosphorin-4-one, 4h-1,3,2-benzodioxaphosphorin-4-one, 2-chloro, salicylchlorophosphite, salicyl chlorophosphite, acmc-1an3b, 2-chloro-4h-1,3,2-benzodioxaphosphinin-4-one, salicylchlorophosphite; van boom's reagent | |
| BVOITXUNGDUXRW-UHFFFAOYNA-N | |
| 2-chloro-1,3,2-benzodioxaphosphinin-4-one | |
| 237010 | |
| 97% |
Safety and Handling
GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
H314-H335
DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
TSCA : No
Recommended Storage : Keep cold
RUO – Research Use Only