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2-Bromo-4-methylaniline, 99%
CAS: 583-68-6 | C7H8BrN | 186.052 g/mol
$80.49 - $259.49
Chemical Identifiers
| CAS | 583-68-6 |
|---|---|
| Molecular Formula | C7H8BrN |
| Molecular Weight (g/mol) | 186.052 |
| MDL Number | MFCD00007635 |
| InChI Key | UVRRJILIXQAAFK-UHFFFAOYSA-N |
| Synonym | 2-bromo-p-toluidine, benzenamine, 2-bromo-4-methyl, 4-amino-3-bromotoluene, 2-bromo-4-methylbenzenamine, p-toluidine, 2-bromo, 2-bromo-4-methyl-phenylamine, 3-bromo-4-aminotoluene, 4-methyl-2-bromoaniline, 2-bromo-4-methyl aniline, 2-bromo-4-methyl-aniline |
| PubChem CID | 11422 |
| IUPAC Name | 2-bromo-4-methylaniline |
| SMILES | CC1=CC(=C(C=C1)N)Br |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAA1381809
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Thermo Scientific Chemicals
A1381809 |
10 g |
Each for $80.49
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AAA1381818
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Thermo Scientific Chemicals
A1381818 |
50 g |
Each for $259.49
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Description
The N-(3, 5-Dichlorophenyl) naphthaldimine was obtained from the reaction of 2-hy- droxynaphthalene-l-carbaldehyde (0.01 mol) with a solution of 2-bromo-4-methylaniline (0.01 mol) in 40 ml of ethanol. Reaction of 2-bromo-4-methylaniline was quite clean, albeit 3,4-diaminotoluene was isolated just in 37% yield after flash chromatography on silica gel. The bromomethylquinoline starting material 16 was synthesized in two steps using an optimized process route by condensing 2-bromo-4-methylaniline.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsThe N-(3, 5-Dichlorophenyl) naphthaldimine was obtained from the reaction of 2-hy- droxynaphthalene-l-carbaldehyde (0.01 mol) with a solution of 2-bromo-4-methylaniline (0.01 mol) in 40 ml of ethanol. Reaction of 2-bromo-4-methylaniline was quite clean, albeit 3,4-diaminotoluene was isolated just in 37% yield after flash chromatography on silica gel. The bromomethylquinoline starting material 16 was synthesized in two steps using an optimized process route by condensing 2-bromo-4-methylaniline.
Solubility
Insoluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
Chemical Identifiers
| 583-68-6 | |
| 186.052 | |
| UVRRJILIXQAAFK-UHFFFAOYSA-N | |
| 11422 | |
| CC1=CC(=C(C=C1)N)Br |
| C7H8BrN | |
| MFCD00007635 | |
| 2-bromo-p-toluidine, benzenamine, 2-bromo-4-methyl, 4-amino-3-bromotoluene, 2-bromo-4-methylbenzenamine, p-toluidine, 2-bromo, 2-bromo-4-methyl-phenylamine, 3-bromo-4-aminotoluene, 4-methyl-2-bromoaniline, 2-bromo-4-methyl aniline, 2-bromo-4-methyl-aniline | |
| 2-bromo-4-methylaniline |
Specifications
| 583-68-6 | |
| 1.494 | |
| >110°C (230°F) | |
| C7H8BrN | |
| MFCD00007635 | |
| UN2810 | |
| 2-bromo-p-toluidine, benzenamine, 2-bromo-4-methyl, 4-amino-3-bromotoluene, 2-bromo-4-methylbenzenamine, p-toluidine, 2-bromo, 2-bromo-4-methyl-phenylamine, 3-bromo-4-aminotoluene, 4-methyl-2-bromoaniline, 2-bromo-4-methyl aniline, 2-bromo-4-methyl-aniline | |
| UVRRJILIXQAAFK-UHFFFAOYSA-N | |
| 2-bromo-4-methylaniline | |
| 11422 | |
| 99% |
| 14°C to 16°C | |
| 240°C to 242°C | |
| Characteristic | |
| 1.603 | |
| 10 g | |
| 1931711 | |
| Insoluble in water. | |
| CC1=CC(=C(C=C1)N)Br | |
| 186.052 | |
| 186.06 | |
| 2-Bromo-4-methylaniline |
Safety and Handling
GHS H Statement
H301-H311-H315-H319
Toxic if swallowed.
Toxic in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
P260-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P305+P351+P338-P311-P312-P314-P330-P332+P313-P361-P363-P501c
H301+H311+H331-H315-H319-H335-H373
DOTInformation : Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: TOXIC, LIQUIDS, ORGANIC, N.O.S.
EINECSNumber : 209-515-7
RTECSNumber : XU4300000
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only