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2,7-Dibromofluorene, 98%

CAS: 16433-88-8 | C13H8Br2 | 324.02 g/mol

$90.19 - $508.41

Chemical Identifiers

CAS 16433-88-8
Molecular Formula C13H8Br2
Molecular Weight (g/mol) 324.02
MDL Number MFCD00019048
InChI Key AVXFJPFSWLMKSG-UHFFFAOYSA-N
PubChem CID 140073
IUPAC Name 2,7-dibromo-9H-fluorene
SMILES BrC1=CC=C2C(CC3=CC(Br)=CC=C23)=C1
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AAA1243709
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A1243709
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Description

Description

2,7-Dibromofluorene is used as a template for the N-carbazole capped oligofluorenes which show potential as hole-transporting materials for organic light emitting devices (OLEDs). It is also used in the synthesis of conjugated polymer, poly[9,9?-bis(6??-N,N,N-trimethylammonium)hexyl)fluorene-co-alt-4,7-(2,1,3-benzothiadiazole) dibromide] (PFBT), used in label-free DNA microarrays, in the preparation of blue photoluminescent unsymmetrically substituted polyfluorene and in the preparation of 2,7-dibromofluorene monomers containing benzyl ether dendrons (generations 1, 2 and 3) in the 9,9?-position of the fluorene ring, such as: 9,9-bis[(3,5-bis(benzyloxy)benzyloxy)methyl]-2,7-dibromofluorene, 9,9-bis[(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy)-methyl] 2,7-dibromo-fluorene, 9,9-bis[(3,5-bis(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy) benzyloxy)-methyl]-2,7-dibromofluorene.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2,7-Dibromofluorene is used as a template for the N-carbazole capped oligofluorenes which show potential as hole-transporting materials for organic light emitting devices (OLEDs). It is also used in the synthesis of conjugated polymer, poly[9,9′-bis(6′′-N,N,N-trimethylammonium)hexyl)fluorene-co-alt-4,7-(2,1,3-benzothiadiazole) dibromide] (PFBT), used in label-free DNA microarrays, in the preparation of blue photoluminescent unsymmetrically substituted polyfluorene and in the preparation of 2,7-dibromofluorene monomers containing benzyl ether dendrons (generations 1, 2 and 3) in the 9,9′-position of the fluorene ring, such as: 9,9-bis[(3,5-bis(benzyloxy)benzyloxy)methyl]-2,7-dibromofluorene, 9,9-bis[(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy)-methyl] 2,7-dibromo-fluorene, 9,9-bis[(3,5-bis(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy) benzyloxy)-methyl]-2,7-dibromofluorene.

Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.
Specifications

Chemical Identifiers

16433-88-8
324.02
AVXFJPFSWLMKSG-UHFFFAOYSA-N
2,7-dibromo-9H-fluorene
C13H8Br2
MFCD00019048
140073
BrC1=CC=C2C(CC3=CC(Br)=CC=C23)=C1

Specifications

16433-88-8
C13H8Br2
10 g
2,7-dibromofluorene, 9h-fluorene, 2,7-dibromo, fluorene, 2,7-dibromo, fluorene,7-dibromo, 2, 7-dibromofluorene, 2,7-di bromo fluorene, 9h-fluorene,7-dibromo, acmc-1c8sn, ksc491i1j
BrC1=CC=C2C(CC3=CC(Br)=CC=C23)=C1
324.02
324.03
2,7-Dibromofluorene
164°C to 167°C
MFCD00019048
2049205
AVXFJPFSWLMKSG-UHFFFAOYSA-N
2,7-dibromo-9H-fluorene
140073
98%
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Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

TSCA : No

Recommended Storage : Ambient temperatures

SDS
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RUO – Research Use Only