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1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate, 98%
CAS: 56602-33-6 | C12H22F6N6OP2 | 442.287 g/mol
$132.79 - $563.74
Chemical Identifiers
| CAS | 56602-33-6 |
|---|---|
| Molecular Formula | C12H22F6N6OP2 |
| Molecular Weight (g/mol) | 442.287 |
| MDL Number | MFCD00011948 |
| InChI Key | MGEVGECQZUIPSV-UHFFFAOYSA-N |
| Synonym | bop reagent, 1h-benzo d 1,2,3 triazol-1-yl oxy tris dimethylamino phosphonium hexafluorophosphate v, castro's reagent, bop-reagent, benzotriazol-1-yloxytris dimethylamino-phosphonium hexafluorophosphate, ccris 2602, castros reagent, tri dimethylamino benzotriazol-1-yloxyphosphonium hexafluorophosphate, benzotriazol-1-yloxy tris dimethylamino phosphonium hexafluorophosphate, 1h-benzotriazol-1-yloxytris dimethylamino phosphonium hexafluorophosphate |
| PubChem CID | 151348 |
| IUPAC Name | benzotriazol-1-yloxy-tris(dimethylamino)phosphanium;hexafluorophosphate |
| SMILES | CN(C)[P+](N(C)C)(N(C)C)ON1C2=CC=CC=C2N=N1.F[P-](F)(F)(F)(F)F |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
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AAA1614006
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Thermo Scientific Chemicals
A1614006 |
5 g |
Each for $132.79
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AAA1614014
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Thermo Scientific Chemicals
A1614014 |
25 g |
Each for $563.74
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Description
1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate is used as a reagent for peptide coupling, lactonization, selective esterification, amidation of alfa amino acids without racemization and synthesis of magnolamide for antioxidative activity and catalyst for 9-acridinecaroboxamide derivative. It is also used as a precursor for the synthesis of phenyl esters of amino acids. It acts as a substitute for (Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate (BOP) reagent.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate is used as a reagent for peptide coupling, lactonization, selective esterification, amidation of alfa amino acids without racemization and synthesis of magnolamide for antioxidative activity and catalyst for 9-acridinecaroboxamide derivative. It is also used as a precursor for the synthesis of phenyl esters of amino acids. It acts as a substitute for (Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate (BOP) reagent.
Solubility
Soluble in methanol, acetone and dichloromethane. Insoluble in water.
Notes
Moisture and light sensitive. Incompatible with strong oxidizing agents. Store in a cool place. Keep the container tightly closed.
Chemical Identifiers
| 56602-33-6 | |
| 442.287 | |
| MGEVGECQZUIPSV-UHFFFAOYSA-N | |
| 151348 | |
| CN(C)[P+](N(C)C)(N(C)C)ON1C2=CC=CC=C2N=N1.F[P-](F)(F)(F)(F)F |
| C12H22F6N6OP2 | |
| MFCD00011948 | |
| bop reagent, 1h-benzo d 1,2,3 triazol-1-yl oxy tris dimethylamino phosphonium hexafluorophosphate v, castro's reagent, bop-reagent, benzotriazol-1-yloxytris dimethylamino-phosphonium hexafluorophosphate, ccris 2602, castros reagent, tri dimethylamino benzotriazol-1-yloxyphosphonium hexafluorophosphate, benzotriazol-1-yloxy tris dimethylamino phosphonium hexafluorophosphate, 1h-benzotriazol-1-yloxytris dimethylamino phosphonium hexafluorophosphate | |
| benzotriazol-1-yloxy-tris(dimethylamino)phosphanium;hexafluorophosphate |
Specifications
| 56602-33-6 | |
| C12H22F6N6OP2 | |
| 5 g | |
| 4287025 | |
| bop reagent, 1h-benzo d 1,2,3 triazol-1-yl oxy tris dimethylamino phosphonium hexafluorophosphate v, castro's reagent, bop-reagent, benzotriazol-1-yloxytris dimethylamino-phosphonium hexafluorophosphate, ccris 2602, castros reagent, tri dimethylamino benzotriazol-1-yloxyphosphonium hexafluorophosphate, benzotriazol-1-yloxy tris dimethylamino phosphonium hexafluorophosphate, 1h-benzotriazol-1-yloxytris dimethylamino phosphonium hexafluorophosphate | |
| MGEVGECQZUIPSV-UHFFFAOYSA-N | |
| benzotriazol-1-yloxy-tris(dimethylamino)phosphanium;hexafluorophosphate | |
| 151348 | |
| 98% |
| ∼138°C (decomposition) | |
| MFCD00011948 | |
| UN1325 | |
| Light and moisture sensitive | |
| Soluble in methanol,acetone and dichloromethane. Insoluble in water. | |
| CN(C)[P+](N(C)C)(N(C)C)ON1C2=CC=CC=C2N=N1.F[P-](F)(F)(F)(F)F | |
| 442.287 | |
| 442.29 | |
| 1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate |
Safety and Handling
GHS H Statement
H228-H315-H319-H335
Flammable solid.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P210-P240-P241-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c
H228-H315-H319-H335-H500
DOTInformation : Transport Hazard Class: 4.1; Packing Group: II; Proper Shipping Name: FLAMMABLE SOLIDS, ORGANIC, N.O.S.
EINECSNumber : 260-279-1
TSCA : No
Recommended Storage : Keep cold; Store under Nitrogen
RUO – Research Use Only