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1,1'-Thiocarbonyldiimidazole, tech 90%
CAS: 6160-65-2 | C7H6N4S | 178.21 g/mol
Supplier: Thermo Scientific Chemicals B2200809
Description
1,1'-Thiocarbonyldiimidazole is used as a reagent for the deoxygenation of alcohols with tributyltin hydride and diols with lithium aluminum hydride. It is also used to deoxygenate carboxylic monosaccharide analogues. Further, it is a useful reagent involved in biochemical synthesis. In addition to this, it is used to prepare 1-[bis-(4-methoxy-phenyl)-methyl]-1H-imidazole by reacting with 4,4'-dimethoxy-benzhydrol.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications1,1′-Thiocarbonyldiimidazole is used as a reagent for the deoxygenation of alcohols with tributyltin hydride and diols with lithium aluminum hydride. It is also used to deoxygenate carboxylic monosaccharide analogues. Further, it is a useful reagent involved in biochemical synthesis. In addition to this, it is used to prepare 1-[bis-(4-methoxy-phenyl)-methyl]-1H-imidazole by reacting with 4,4′-dimethoxy-benzhydrol.
Solubility
Soluble in terahydrofuran, toluene and dichloromethane.
Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Store in a cool place. Incompatible with strong oxidizing agents and strong acids.
Specifications
1, 1'-Thiocarbonyldiimidazole | |
98°C to 102°C | |
C7H6N4S | |
10 g | |
Moisture sensitive | |
Soluble in terahydrofuran,toluene and dichloromethane. | |
S=C(N1C=CN=C1)N1C=CN=C1 | |
178.21 | |
178.22 | |
Technical |
6160-65-2 | |
0.95 | |
MFCD00005289 | |
609349 | |
1,1'-thiocarbonyldiimidazole, thiocarbonyldiimidazole, n,n'-thiocarbonyldiimidazole, di 1h-imidazol-1-yl methanethione, 1,1-thiocarbonyldiimidazole, di imidazol-1-yl methanethione, n,n'-thiocarbonyldiimidazole tcdi, 1h-imidazole, 1,1'-carbonothioylbis, n,n-thiocarbonyldiimidazole, 1,1'-carbonothioylbis-1h-imidazole | |
RAFNCPHFRHZCPS-UHFFFAOYSA-N | |
di(imidazol-1-yl)methanethione | |
80264 | |
90% |
Chemical Identifiers
6160-65-2 | |
178.21 | |
RAFNCPHFRHZCPS-UHFFFAOYSA-N | |
80264 | |
S=C(N1C=CN=C1)N1C=CN=C1 |
C7H6N4S | |
MFCD00005289 | |
1,1'-thiocarbonyldiimidazole, thiocarbonyldiimidazole, n,n'-thiocarbonyldiimidazole, di 1h-imidazol-1-yl methanethione, 1,1-thiocarbonyldiimidazole, di imidazol-1-yl methanethione, n,n'-thiocarbonyldiimidazole tcdi, 1h-imidazole, 1,1'-carbonothioylbis, n,n-thiocarbonyldiimidazole, 1,1'-carbonothioylbis-1h-imidazole | |
di(imidazol-1-yl)methanethione |
Safety and Handling
GHS H Statement
H315-H319-H335
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
H315-H319-H335
EINECSNumber : 228-183-4
TSCA : No
storageNote1 : Moisture Sensitive
Recommended Storage : Keep cold; Store under Argon
RUO – Research Use Only